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Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes
http://hdl.handle.net/2237/26253
http://hdl.handle.net/2237/262531820e813-3dbc-4c42-aaa5-f8538c4cf3f9
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-05-09 | |||||
タイトル | ||||||
タイトル | Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes | |||||
言語 | en | |||||
著者 |
Yamamoto, Yoshihiko
× Yamamoto, Yoshihiko× Nishimura, Kei-ichiro× Shibuya, Masatoshi |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aitDP7XGZQ7EvxB3zTx3].” | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cycloisomerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | enediyne | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | indenylidenecycloalkane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ruthenium catalyst | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | spirocycle | |||||
抄録 | ||||||
内容記述 | In the presence of a neutral ruthenium catalyst, Cp*RuCl(cod), 1,5,10-enediynes bearing a styryl terminal underwent cycloisomerization to afford exocyclic 1,3-dienes with an indenylidene moiety. The reaction mechanism is proposed on the basis of the results of control experiments and density functional calculations. The transformations of the obtained cyclization products were also investigated to demonstrate the synthetic potential of this method. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acscatal.6b03322 | |||||
ISSN | ||||||
収録物識別子タイプ | EISSN | |||||
収録物識別子 | 2155-5435 | |||||
書誌情報 |
en : ACS Catalysis 巻 7, 号 2, p. 1101-1107, 発行日 2016-12-22 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1021/acscatal.6b03322 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/26253 | |||||
識別子タイプ | HDL |