{"_buckets": {"deposit": "a6c15d69-0b5c-4449-8745-cf127b6168c7"}, "_deposit": {"id": "24038", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24038"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024038"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-12-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "1107", "bibliographicPageStart": "1101", "bibliographicVolumeNumber": "7", "bibliographic_titles": [{"bibliographic_title": "ACS Catalysis"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "In the presence of a neutral ruthenium catalyst, Cp*RuCl(cod), 1,5,10-enediynes bearing a styryl terminal underwent cycloisomerization to afford exocyclic 1,3-dienes with an indenylidene moiety. The reaction mechanism is proposed on the basis of the results of control experiments and density functional calculations. The transformations of the obtained cyclization products were also investigated to demonstrate the synthetic potential of this method.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1021/acscatal.6b03322"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26253"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aitDP7XGZQ7EvxB3zTx3].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2155-5435", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko"}], "nameIdentifiers": [{"nameIdentifier": "71355", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishimura, Kei-ichiro"}], "nameIdentifiers": [{"nameIdentifier": "71356", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shibuya, Masatoshi"}], "nameIdentifiers": [{"nameIdentifier": "71357", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-12-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACS_Cat_MS_RevMarked.pdf", "filesize": [{"value": "4.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 4800000.0, "url": {"label": "ACS_Cat_MS_RevMarked.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017/12/22", "url": "https://nagoya.repo.nii.ac.jp/record/24038/files/ACS_Cat_MS_RevMarked.pdf"}, "version_id": "1e1a4c19-e966-4704-b7ce-b9b86068b9f8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "cycloisomerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "enediyne", "subitem_subject_scheme": "Other"}, {"subitem_subject": "indenylidenecycloalkane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ruthenium catalyst", "subitem_subject_scheme": "Other"}, {"subitem_subject": "spirocycle", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/26253", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-05-09"}, "publish_date": "2017-05-09", "publish_status": "0", "recid": "24038", "relation": {}, "relation_version_is_last": true, "title": ["Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes"], "weko_shared_id": null}