{"_buckets": {"deposit": "0fe266ca-953a-49e3-aa86-2a5170437cb4"}, "_deposit": {"id": "24074", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24074"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024074"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-02-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "457", "bibliographicPageStart": "455", "bibliographicVolumeNumber": "58", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron Letters"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A practical synthesis of ortho-silyl-substituted phenol from ortho-bromophenyl silyl ethers without using RLi is described. Various ortho-bromophenyl silyl ethers are treated with commercially available Mg turnings, which are easy to handle in air, and transfer of the silyl group to the ortho-position occurs in good to high yields. Selective mono-magnesiation of 2,6-dibromophenyl silyl ether is observed even in the presence of excess Mg, and ortho-bromo-6-silylphenol is obtained as the predominant product. The obtained ortho-silyl-substituted phenol is formylated with (CH2O)n/MgCl2/Et3N, and then condensation with a diamine leads to a silyl-substituted salen-type ligand in a good yield. This scheme is suitable for the large scale synthesis of silyl-substituted salen-type ligands bearing imine groups.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "https://doi.org/10.1016/j.tetlet.2016.12.052"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26286"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hasegawa, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "71461", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kishida, Hisanori"}], "nameIdentifiers": [{"nameIdentifier": "71462", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nomura, Nobuyoshi"}], "nameIdentifiers": [{"nameIdentifier": "71463", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "3_Manuscript.pdf", "filesize": [{"value": "375.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 375800.0, "url": {"label": "3_Manuscript.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019/02/01", "url": "https://nagoya.repo.nii.ac.jp/record/24074/files/3_Manuscript.pdf"}, "version_id": "c76438bb-bfff-4d3a-8e5d-a8fbe95fc775"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)"}]}, "item_type_id": "10", "owner": "1", "path": ["643/666/667"], "permalink_uri": "http://hdl.handle.net/2237/26286", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-05-11"}, "publish_date": "2017-05-11", "publish_status": "0", "recid": "24074", "relation": {}, "relation_version_is_last": true, "title": ["A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)"], "weko_shared_id": null}