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Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)
http://hdl.handle.net/2237/26627
http://hdl.handle.net/2237/266276e5c8e7e-6335-45d5-bc71-abd65100a4f2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JACS.pdf ファイル公開：2018/02/22 (377.2 kB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-06-09 | |||||
| タイトル | ||||||
| タイトル | Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4) | |||||
| 言語 | en | |||||
| 著者 |
Tsukahara, Nana
× Tsukahara, Nana× Asakawa, Hiroki× Lee, Ka-Ho× Lin, Zhenyang× Yamashita, Makoto |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aTWSauz2HwYP55PtkXZP].” | |||||
| 言語 | en | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H2 (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H–H and B–B bonds. DFT calculations suggested a diarylboryl anion character for the transition state. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/jacs.7b00924 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0002-7863 | |||||
| 書誌情報 |
en : Journal of the American Chemical Society 巻 139, 号 7, p. 2593-2596, 発行日 2017-02-22 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1021/jacs.7b00924 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/26627 | |||||
| 識別子タイプ | HDL | |||||
