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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)

http://hdl.handle.net/2237/26627
6e5c8e7e-6335-45d5-bc71-abd65100a4f2
名前 / ファイル ライセンス アクション
JACS.pdf JACS.pdf ファイル公開:2018/02/22 (377.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-06-09
タイトル
タイトル Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)
著者 Tsukahara, Nana

× Tsukahara, Nana

WEKO 72338

Tsukahara, Nana

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Asakawa, Hiroki

× Asakawa, Hiroki

WEKO 72339

Asakawa, Hiroki

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Lee, Ka-Ho

× Lee, Ka-Ho

WEKO 72340

Lee, Ka-Ho

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Lin, Zhenyang

× Lin, Zhenyang

WEKO 72341

Lin, Zhenyang

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 72342

Yamashita, Makoto

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権利
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aTWSauz2HwYP55PtkXZP].”
抄録
内容記述 Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H2 (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H–H and B–B bonds. DFT calculations suggested a diarylboryl anion character for the transition state.
内容記述タイプ Abstract
出版者
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0002-7863
書誌情報 Journal of the American Chemical Society

巻 139, 号 7, p. 2593-2596, 発行日 2017-02-22
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1021/jacs.7b00924
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/26627
識別子タイプ HDL
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