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Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)
http://hdl.handle.net/2237/26627
6e5c8e7e-6335-45d5-bc71-abd65100a4f2
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-06-09 | |||||
タイトル | ||||||
タイトル | Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4) | |||||
著者 |
Tsukahara, Nana
× Tsukahara, Nana× Asakawa, Hiroki× Lee, Ka-Ho× Lin, Zhenyang× Yamashita, Makoto |
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権利 | ||||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aTWSauz2HwYP55PtkXZP].” | |||||
抄録 | ||||||
内容記述 | Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H2 (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H–H and B–B bonds. DFT calculations suggested a diarylboryl anion character for the transition state. | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0002-7863 | |||||
書誌情報 |
Journal of the American Chemical Society 巻 139, 号 7, p. 2593-2596, 発行日 2017-02-22 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1021/jacs.7b00924 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/26627 | |||||
識別子タイプ | HDL |