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Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
http://hdl.handle.net/2237/26630
http://hdl.handle.net/2237/266304687760b-f6aa-49bb-9102-083480998e19
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ACIE.pdf ファイル公開：2018/02/01 (802.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-06-09 | |||||
| タイトル | ||||||
| タイトル | Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene | |||||
| 言語 | en | |||||
| 著者 |
Asami, Shun-suke
× Asami, Shun-suke× Ishida, Shintaro× Iwamoto, Takeaki× Suzuki, Katsunori× Yamashita, Makoto |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | This is the peer reviewed version of the following article: [S.-s. Asami, S. Ishida, T. Iwamoto, K. Suzuki, M. Yamashita, Angew. Chem. Int. Ed. 2017, 56, 1658.<br/>], which has been published in final form at [http://doi.org/10.1002/anie.201611762]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Radical anions of a diphosphene with two boryl substituents were isolated and characterized by single-crystal X-ray diffraction, electron spin resonance (ESR), and UV/Vis absorption spectroscopy as well as DFT calculations. Structural analysis of the radical anions revealed an elongation of the P=P bond and a contraction of the B−P bonds relative to the neutral diphosphene. The UV/Vis spectra of these radical anions showed a strong absorption in the visible region, which was assigned to SOMO-related transitions on the basis of DFT calculations. The ESR spectra revealed that the hyperfine coupling constant with the phosphorus nuclei is the smallest that has been reported thus far. The results of the DFT calculations furthermore suggest that this should be attributed to a soaking of electron spin to the vacant p orbitals of the boryl substituents. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/anie.201611762 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1433-7851 | |||||
| 書誌情報 |
en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 巻 56, 号 6, p. 1658-1662, 発行日 2017-02-01 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1002/anie.201611762 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/26630 | |||||
| 識別子タイプ | HDL | |||||
