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Benzonorcorrole Ni^II Complexes : Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion
http://hdl.handle.net/2237/00028304
http://hdl.handle.net/2237/000283047f73f209-3f24-42d3-9605-3b8019c53703
名前 / ファイル | ライセンス | アクション |
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manuscript (5.9 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-06-13 | |||||
タイトル | ||||||
タイトル | Benzonorcorrole Ni^II Complexes : Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion | |||||
言語 | en | |||||
著者 |
Yoshida, Takuya
× Yoshida, Takuya× Takahashi, Kohtaro× Ide, Yuki× Kishi, Ryohei× Fujiyoshi, Jun-ya× Lee, Sangsu× Hiraoka, Yuya× Kim, Dongho× Nakano, Masayoshi× Ikeue, Takahisa× Yamada, Hiroko× Shinokubo, Hiroshi |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [T. Yoshida, K. Takahashi, Y. Ide, R. Kishi, J.-y. Fujiyoshi, S. Lee, Y. Hiraoka, D. Kim, M. Nakano, T. Ikeue, H. Yamada, H. Shinokubo, Angew. Chem. Int. Ed. 2018, 57, 2209. ], which has been published in final form at [https://doi.org/10.1002/anie.201712961]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
抄録 | ||||||
内容記述 | Fused benzene rings to antiaromatic compounds generally improve their stability but attenuate their antiaromaticity. The opposite case is now reported. Ni^II benzonorcorroles were synthesized and the effect of benzo‐fusion on the antiaromaticity was elucidated. The benzo‐fusion resulted in significant decrease of the HOMO–LUMO gaps and enhancement of the paratropic ring current effect. Furthermore, the introduction of the benzo groups induced singlet diradical character in the antiaromatic porphyrinoid. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019-02-19 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/anie.201712961 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1433-7851 | |||||
書誌情報 |
en : Angewandte Chemie International Edition 巻 57, 号 8, p. 2209-2213, 発行日 2018-02-19 |
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著者版フラグ | ||||||
値 | author |