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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Benzonorcorrole Ni^II Complexes : Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion

http://hdl.handle.net/2237/00028304
http://hdl.handle.net/2237/00028304
7f73f209-3f24-42d3-9605-3b8019c53703
名前 / ファイル ライセンス アクション
manuscript.pdf manuscript (5.9 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-06-13
タイトル
タイトル Benzonorcorrole Ni^II Complexes : Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion
言語 en
著者 Yoshida, Takuya

× Yoshida, Takuya

WEKO 78271

en Yoshida, Takuya

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Takahashi, Kohtaro

× Takahashi, Kohtaro

WEKO 78272

en Takahashi, Kohtaro

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Ide, Yuki

× Ide, Yuki

WEKO 78273

en Ide, Yuki

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Kishi, Ryohei

× Kishi, Ryohei

WEKO 78274

en Kishi, Ryohei

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Fujiyoshi, Jun-ya

× Fujiyoshi, Jun-ya

WEKO 78275

en Fujiyoshi, Jun-ya

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Lee, Sangsu

× Lee, Sangsu

WEKO 78276

en Lee, Sangsu

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Hiraoka, Yuya

× Hiraoka, Yuya

WEKO 78277

en Hiraoka, Yuya

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Kim, Dongho

× Kim, Dongho

WEKO 78278

en Kim, Dongho

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Nakano, Masayoshi

× Nakano, Masayoshi

WEKO 78279

en Nakano, Masayoshi

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Ikeue, Takahisa

× Ikeue, Takahisa

WEKO 78280

en Ikeue, Takahisa

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Yamada, Hiroko

× Yamada, Hiroko

WEKO 78281

en Yamada, Hiroko

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Shinokubo, Hiroshi

× Shinokubo, Hiroshi

WEKO 78282

en Shinokubo, Hiroshi

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [T. Yoshida, K. Takahashi, Y. Ide, R. Kishi, J.-y. Fujiyoshi, S. Lee, Y. Hiraoka, D. Kim, M. Nakano, T. Ikeue, H. Yamada, H. Shinokubo, Angew. Chem. Int. Ed. 2018, 57, 2209. ], which has been published in final form at [https://doi.org/10.1002/anie.201712961]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 Fused benzene rings to antiaromatic compounds generally improve their stability but attenuate their antiaromaticity. The opposite case is now reported. Ni^II benzonorcorroles were synthesized and the effect of benzo‐fusion on the antiaromaticity was elucidated. The benzo‐fusion resulted in significant decrease of the HOMO–LUMO gaps and enhancement of the paratropic ring current effect. Furthermore, the introduction of the benzo groups induced singlet diradical character in the antiaromatic porphyrinoid.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2019-02-19
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201712961
ISSN
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : Angewandte Chemie International Edition

巻 57, 号 8, p. 2209-2213, 発行日 2018-02-19
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