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Metal-free transesterification catalyzed by tetramethylammonium methyl carbonate
http://hdl.handle.net/2237/00028332
http://hdl.handle.net/2237/000283321ecde2eb-4e88-4625-a3e8-92e2966d1e6b
名前 / ファイル | ライセンス | アクション |
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Manuscript-revision2 (1.6 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-07-03 | |||||
タイトル | ||||||
タイトル | Metal-free transesterification catalyzed by tetramethylammonium methyl carbonate | |||||
言語 | en | |||||
著者 |
Hatano, Manabu
× Hatano, Manabu× Tabata, Yuji× Yoshida, Yurika× Toh, Kohei× Yamashita, Kenji× Ogura, Yoshihiro× Ishihara, Kazuaki |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
抄録 | ||||||
内容記述 | Environmentally benign metal-free tetramethylammonium methyl carbonate is effective as a catalyst for the chemoselective, scalable, and reusable transesterification of various esters and alcohols in common organic solvents. In situ-generated highly active species, tetramethylammonium alkoxides, can greatly avoid self-decomposition at ≤110 °C, and are reusable. In particular, chelating substrates, such as amino alcohols, diols, triols, sugar derivatives, alkaloids, α-amino acid esters, etc., which deactivate conventional metal salt catalysts, can be used. A 100 gram scale biodiesel production was also demonstrated. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019/03/21 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Royal Society of Chemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/C7GC03858E | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1463-9262 | |||||
書誌情報 |
en : Green Chemistry 巻 20, 号 6, p. 1193-1198, 発行日 2018-03-21 |
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著者版フラグ | ||||||
値 | author |