{"_buckets": {"deposit": "e7998980-ce1b-44e8-a07b-f9bf9b5bfed0"}, "_deposit": {"id": "26351", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26351"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026351", "sets": ["322"]}, "author_link": ["85207", "85208", "85209", "85210", "85211"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-05-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "6114", "bibliographicPageStart": "6109", "bibliographicVolumeNumber": "57", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The reaction of highly Lewis acidic tetra(o‐tolyl)diborane(4) with CO afforded a mixture of boraindane and boroxine by the cleavage of the C≡O triple bond. 13C labeling experiments confirmed that the carbon atom in the boraindane stems from CO. Simultaneously, formation of boroxine 3 could be considered as borylene transfer to capture the oxygen atom from CO. The reaction of diborane(4) with tBu−NC afforded an azaallene, while the reaction with Xyl−NC furnished cyclic compounds by direct C−H borylations. ", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2019-05-22", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201800878", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [Y. Katsuma, N. Tsukahara, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2018, 57, 6109.], which has been published in final form at [https://doi.org/10.1002/anie.201800878]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "PISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN（Online）", "attribute_value_mlt": [{"subitem_source_identifier": "1521-3773", "subitem_source_identifier_type": "EISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Katsuma, Yuhei", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85207", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tsukahara, Nana", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85208", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wu, Linlin", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85209", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lin, Zhenyang", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85210", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85211", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-05-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20180314_Text.pdf", "filesize": [{"value": "613.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 613500.0, "url": {"label": "20180314_Text", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/26351/files/20180314_Text.pdf"}, "version_id": "9ec4d792-e242-4b7c-a7d4-985eb239c8ca"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "bond cleavage", "subitem_subject_scheme": "Other"}, {"subitem_subject": "carbon monoxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "diborane(4)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "isocyanide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "triple bonds", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00028554", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-09-11"}, "publish_date": "2018-09-11", "publish_status": "0", "recid": "26351", "relation": {}, "relation_version_is_last": true, "title": ["Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations"], "weko_shared_id": -1}