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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations

http://hdl.handle.net/2237/00028554
http://hdl.handle.net/2237/00028554
a30de669-aced-4d18-a9fe-fb57d7cf9a33
名前 / ファイル ライセンス アクション
20180314_Text.pdf 20180314_Text (613.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-09-11
タイトル
タイトル Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations
言語 en
著者 Katsuma, Yuhei

× Katsuma, Yuhei

WEKO 85207

en Katsuma, Yuhei

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Tsukahara, Nana

× Tsukahara, Nana

WEKO 85208

en Tsukahara, Nana

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Wu, Linlin

× Wu, Linlin

WEKO 85209

en Wu, Linlin

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Lin, Zhenyang

× Lin, Zhenyang

WEKO 85210

en Lin, Zhenyang

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 85211

en Yamashita, Makoto

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [Y. Katsuma, N. Tsukahara, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2018, 57, 6109.], which has been published in final form at [https://doi.org/10.1002/anie.201800878]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
キーワード
主題Scheme Other
主題 bond cleavage
キーワード
主題Scheme Other
主題 carbon monoxide
キーワード
主題Scheme Other
主題 diborane(4)
キーワード
主題Scheme Other
主題 isocyanide
キーワード
主題Scheme Other
主題 triple bonds
抄録
内容記述 The reaction of highly Lewis acidic tetra(o‐tolyl)diborane(4) with CO afforded a mixture of boraindane and boroxine by the cleavage of the C≡O triple bond. 13C labeling experiments confirmed that the carbon atom in the boraindane stems from CO. Simultaneously, formation of boroxine 3 could be considered as borylene transfer to capture the oxygen atom from CO. The reaction of diborane(4) with tBu−NC afforded an azaallene, while the reaction with Xyl−NC furnished cyclic compounds by direct C−H borylations.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2019-05-22
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201800878
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 1433-7851
ISSN(Online)
収録物識別子タイプ EISSN
収録物識別子 1521-3773
書誌情報 en : Angewandte Chemie International Edition

巻 57, 号 21, p. 6109-6114, 発行日 2018-05-22
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