{"_buckets": {"deposit": "e7998980-ce1b-44e8-a07b-f9bf9b5bfed0"}, "_deposit": {"id": "26351", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26351"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026351"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-05-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "6114", "bibliographicPageStart": "6109", "bibliographicVolumeNumber": "57", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The reaction of highly Lewis acidic tetra(o\u2010tolyl)diborane(4) with CO afforded a mixture of boraindane and boroxine by the cleavage of the C\u2261O triple bond. 13C labeling experiments confirmed that the carbon atom in the boraindane stems from CO. Simultaneously, formation of boroxine 3 could be considered as borylene transfer to capture the oxygen atom from CO. The reaction of diborane(4) with tBu\u2212NC afforded an azaallene, while the reaction with Xyl\u2212NC furnished cyclic compounds by direct C\u2212H borylations. ", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-05-22", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201800878", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Y. Katsuma, N. Tsukahara, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2018, 57, 6109.], which has been published in final form at [https://doi.org/10.1002/anie.201800878]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1521-3773", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Katsuma, Yuhei"}], "nameIdentifiers": [{"nameIdentifier": "85207", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tsukahara, Nana"}], "nameIdentifiers": [{"nameIdentifier": "85208", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wu, Linlin"}], "nameIdentifiers": [{"nameIdentifier": "85209", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lin, Zhenyang"}], "nameIdentifiers": [{"nameIdentifier": "85210", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "85211", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-05-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20180314_Text.pdf", "filesize": [{"value": "613.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 613500.0, "url": {"label": "20180314_Text", "url": "https://nagoya.repo.nii.ac.jp/record/26351/files/20180314_Text.pdf"}, "version_id": "9ec4d792-e242-4b7c-a7d4-985eb239c8ca"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "bond cleavage", "subitem_subject_scheme": "Other"}, {"subitem_subject": "carbon monoxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "diborane(4)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "isocyanide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "triple bonds", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C\u2261O Triple Bond and Direct C\u2212H Borylations", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C\u2261O Triple Bond and Direct C\u2212H Borylations"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00028554", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-09-11"}, "publish_date": "2018-09-11", "publish_status": "0", "recid": "26351", "relation": {}, "relation_version_is_last": true, "title": ["Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C\u2261O Triple Bond and Direct C\u2212H Borylations"], "weko_shared_id": null}