WEKO3
アイテム
Brønsted Acid/Lewis Base Hybrid Complexes
http://hdl.handle.net/2237/00028557
http://hdl.handle.net/2237/0002855702260d76-c16c-46ef-adb6-80c8df0561f9
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
chapter (3.7 MB)
|
|
| Item type | 図書の一部 / Book Chapter(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-09-11 | |||||
| タイトル | ||||||
| タイトル | Brønsted Acid/Lewis Base Hybrid Complexes | |||||
| 言語 | en | |||||
| 著者 |
Hatano, Manabu
× Hatano, Manabu× Ishihara, Kazuaki |
|||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Acid–base catalyst | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | BINOL | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Boron | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Magnesium | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Supramolecular catalyst | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Recent progress on our Brønsted acid/Lewis base hybrid complexes in some asymmetric catalyses is reviewed. Based on the rational design of conjugated acid–base catalysts, tailor-made supramolecular catalysts can show remarkable catalytic activity and higher-ordered selectivities that cannot be realized by ready-made single-molecule catalysts. The chiral supramolecular magnesium(II) binaphtholate complexes trigger the highly enantioselective 1,4-hydrophosphinylation and 1,2-hydrophosphonylation of α,β-unsaturated carbonyl compounds, direct Mannich-type reaction, and hetero-Diels–Alder reaction. Moreover, the advanced supramolecular catalysts are prepared in situ from chiral 3,3′-disubstituted binaphthols and biphenols, arylboronic acid, and B(C6F5)3, for promoting the anomalous endo-/exo-selective Diels–Alder reaction. The specific mechanism and deep insights into the possible key intermediates are discussed on the basis of rational design of chiral supramolecular Brønsted acid/Lewis base hybrid catalysts as artificial enzymes. | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | First Online: 11 August 2015. | |||||
| 出版者 | ||||||
| 出版者 | Springer | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_3248 | |||||
| 資源タイプ | book part | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1007/3418_2015_143 | |||||
| ISBN | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | ISBN | |||||
| 関連識別子 | 978-3-319-70804-1 | |||||
| ISSN | ||||||
| 関連タイプ | isPartOf | |||||
| 識別子タイプ | ISSN | |||||
| 関連識別子 | 1436-6002 | |||||
| 図書名 | ||||||
| 収録物名 | Chiral Lewis Acids | |||||
| 書誌情報 |
巻 62, p. 91-120, 発行日 2018 |
|||||
| 著者版フラグ | ||||||
| 値 | author | |||||
| シリーズ | ||||||
| 関連名称 | Topics in Organometallic Chemistry book series (TOPORGAN, volume 62) | |||||
