{"_buckets": {"deposit": "7b51158f-4949-46ee-97de-e167d3664e42"}, "_deposit": {"id": "26373", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26373"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026373", "sets": ["322"]}, "author_link": ["85307", "85308", "85309", "85310", "85311", "85312"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-05-23", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageEnd": "6342", "bibliographicPageStart": "6336", "bibliographicVolumeNumber": "140", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We designed and synthesized molecular tweezers consisting of nitrogen-embedded buckybowl subunits. The judicious choice of the covalent linkers modulated their binding strength with C60 or C70 in solution. Titration studies by optical and 1H NMR analyses revealed a 1:1 composition of the resulting complexes. X-ray diffraction analysis elucidated their solid-state structures, in which two azabuckybowl units surround one fullerene molecule. The large association constants stabilize the complexes toward redox reactions and the purification process on silica-gel column chromatography. The linker enabled tuning of the cavity size for binding of fullerenes, achieving complementary fullerene hosts for C60 and C70: the carbazole-bridged dimer preferentially associates with C70 over C60, while the phenanthrene-bridged dimer interacts with C60 more strongly than C70. Electrochemical analysis in combination with density functional theory calculations indicated the existence of intermolecular charge-transfer interactions between the buckybowl units and the fullerenes. Nonlinear optical measurements showed that the two-photon absorption cross sections of the molecular tweezers are enhanced upon association with fullerenes.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2019-05-23", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.8b02327", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-Af3K7B4ddX4FGds57Hw5].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "PISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN（Online）", "attribute_value_mlt": [{"subitem_source_identifier": "1520-5126", "subitem_source_identifier_type": "EISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takeda, Motoki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85307", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroto, Satoru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85308", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoi, Hiroki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85309", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lee, Sangsu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85310", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Dongho", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85311", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "85312", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-05-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "8416_MT_rev.pdf", "filesize": [{"value": "3.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 3400000.0, "url": {"label": "8416_MT_rev", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/26373/files/8416_MT_rev.pdf"}, "version_id": "222cfd73-c874-44af-b2ba-f91d0f469f97"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00028576", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-09-13"}, "publish_date": "2018-09-13", "publish_status": "0", "recid": "26373", "relation": {}, "relation_version_is_last": true, "title": ["Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors"], "weko_shared_id": -1}