{"_buckets": {"deposit": "7b51158f-4949-46ee-97de-e167d3664e42"}, "_deposit": {"id": "26373", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26373"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026373"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-05-23", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageEnd": "6342", "bibliographicPageStart": "6336", "bibliographicVolumeNumber": "140", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "We designed and synthesized molecular tweezers consisting of nitrogen-embedded buckybowl subunits. The judicious choice of the covalent linkers modulated their binding strength with C60 or C70 in solution. Titration studies by optical and 1H NMR analyses revealed a 1:1 composition of the resulting complexes. X-ray diffraction analysis elucidated their solid-state structures, in which two azabuckybowl units surround one fullerene molecule. The large association constants stabilize the complexes toward redox reactions and the purification process on silica-gel column chromatography. The linker enabled tuning of the cavity size for binding of fullerenes, achieving complementary fullerene hosts for C60 and C70: the carbazole-bridged dimer preferentially associates with C70 over C60, while the phenanthrene-bridged dimer interacts with C60 more strongly than C70. Electrochemical analysis in combination with density functional theory calculations indicated the existence of intermolecular charge-transfer interactions between the buckybowl units and the fullerenes. Nonlinear optical measurements showed that the two-photon absorption cross sections of the molecular tweezers are enhanced upon association with fullerenes.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-05-23", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.8b02327", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-Af3K7B4ddX4FGds57Hw5].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1520-5126", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takeda, Motoki"}], "nameIdentifiers": [{"nameIdentifier": "85307", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroto, Satoru"}], "nameIdentifiers": [{"nameIdentifier": "85308", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoi, Hiroki"}], "nameIdentifiers": [{"nameIdentifier": "85309", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lee, Sangsu"}], "nameIdentifiers": [{"nameIdentifier": "85310", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Dongho"}], "nameIdentifiers": [{"nameIdentifier": "85311", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "85312", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-05-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "8416_MT_rev.pdf", "filesize": [{"value": "3.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 3400000.0, "url": {"label": "8416_MT_rev", "url": "https://nagoya.repo.nii.ac.jp/record/26373/files/8416_MT_rev.pdf"}, "version_id": "222cfd73-c874-44af-b2ba-f91d0f469f97"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00028576", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-09-13"}, "publish_date": "2018-09-13", "publish_status": "0", "recid": "26373", "relation": {}, "relation_version_is_last": true, "title": ["Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors"], "weko_shared_id": null}