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  1. H120 物質科学国際研究センター
  2. H120a 雑誌掲載論文
  3. 学術雑誌

Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides

http://hdl.handle.net/2237/00030147
http://hdl.handle.net/2237/00030147
bec47a0f-086b-459f-9042-1067147e14ef
名前 / ファイル ライセンス アクション
AJOC181113_3.pdf AJOC181113_3 (448.4 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-05-09
タイトル
タイトル Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides
言語 en
著者 Kitamura, Yuki

× Kitamura, Yuki

WEKO 90991

en Kitamura, Yuki

Search repository
Murata, Yuki

× Murata, Yuki

WEKO 90992

en Murata, Yuki

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Oguri, Ayaka

× Oguri, Ayaka

WEKO 90993

en Oguri, Ayaka

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Matsumura, Mio

× Matsumura, Mio

WEKO 90994

en Matsumura, Mio

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Kakusawa, Naoki

× Kakusawa, Naoki

WEKO 90995

en Kakusawa, Naoki

Search repository
Naka, Hiroshi

× Naka, Hiroshi

WEKO 90996

en Naka, Hiroshi

Search repository
Yasuike, Shuji

× Yasuike, Shuji

WEKO 90997

en Yasuike, Shuji

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 "This is the peer reviewed version of the following article: [Y. Kitamura, Y. Murata, A. Oguri, M. Matsumura, N. Kakusawa, H. Naka, S. Yasuike, Asian J. Org. Chem. 2019, 8, 138.], which has been published in final form at [https://doi.org/10.1002/ajoc.201800654]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."
キーワード
主題Scheme Other
主題 Antimony
キーワード
主題Scheme Other
主題 Thiophene
キーワード
主題Scheme Other
主題 Palladium catalyst
キーワード
主題Scheme Other
主題 Pentavalent triarylantimony difluoride
キーワード
主題Scheme Other
主題 β-selective C−H arylation
抄録
内容記述 Regioselective C−H arylation using pentavalent organoantimony compounds as a new class of arylating reagents is described. The reaction of thiophenes with triarylantimony difluorides in the presence of 5 mol% of Pd(OAc)2 and 2 equiv. CuCl2 at 80 °C under aerobic conditions afforded the β‐arylated thiophene derivatives in moderate‐to‐high yields. The reaction is sensitive to the electronic nature of the triarylantimony difluorides – those bearing an electron‐donating group on the phenyl ring showed higher reactivity than those have an electron‐withdrawing group.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-01-01
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/ajoc.201800654
ISSN(Online)
収録物識別子タイプ EISSN
収録物識別子 2193-5807
書誌情報 en : Asian Journal of Organic Chemistry

巻 8, 号 1, p. 138-143, 発行日 2019-01
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