{"_buckets": {"deposit": "0eecf8ab-8678-43ce-9d52-26ebfd44323e"}, "_deposit": {"id": "27948", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27948"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027948", "sets": ["1919"]}, "author_link": ["90991", "90992", "90993", "90994", "90995", "90996", "90997"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "143", "bibliographicPageStart": "138", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{"bibliographic_title": "Asian Journal of Organic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Regioselective C−H arylation using pentavalent organoantimony compounds as a new class of arylating reagents is described. The reaction of thiophenes with triarylantimony difluorides in the presence of 5 mol% of Pd(OAc)2 and 2 equiv. CuCl2 at 80 °C under aerobic conditions afforded the β‐arylated thiophene derivatives in moderate‐to‐high yields. The reaction is sensitive to the electronic nature of the triarylantimony difluorides – those bearing an electron‐donating group on the phenyl ring showed higher reactivity than those have an electron‐withdrawing group.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2020-01-01", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ajoc.201800654", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": " \t\"This is the peer reviewed version of the following article: [Y. Kitamura, Y. Murata, A. Oguri, M. Matsumura, N. Kakusawa, H. Naka, S. Yasuike, Asian J. Org. Chem. 2019, 8, 138.], which has been published in final form at [https://doi.org/10.1002/ajoc.201800654]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\"", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_62": {"attribute_name": "ISSN（Online）", "attribute_value_mlt": [{"subitem_source_identifier": "2193-5807", "subitem_source_identifier_type": "EISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kitamura, Yuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90991", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Murata, Yuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90992", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oguri, Ayaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90993", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsumura, Mio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90994", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kakusawa, Naoki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90995", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Naka, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90996", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasuike, Shuji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90997", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-01-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AJOC181113_3.pdf", "filesize": [{"value": "448.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 448400.0, "url": {"label": "AJOC181113_3", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/27948/files/AJOC181113_3.pdf"}, "version_id": "0e99f951-9af7-41df-afe0-cdbdd5958df0"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Antimony", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Thiophene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Palladium catalyst", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pentavalent triarylantimony difluoride", "subitem_subject_scheme": "Other"}, {"subitem_subject": "β-selective C−H arylation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1919"], "permalink_uri": "http://hdl.handle.net/2237/00030147", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-05-09"}, "publish_date": "2019-05-09", "publish_status": "0", "recid": "27948", "relation": {}, "relation_version_is_last": true, "title": ["Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides"], "weko_shared_id": -1}