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Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides
http://hdl.handle.net/2237/00030147
http://hdl.handle.net/2237/00030147bec47a0f-086b-459f-9042-1067147e14ef
名前 / ファイル | ライセンス | アクション |
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AJOC181113_3 (448.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-05-09 | |||||
タイトル | ||||||
タイトル | Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides | |||||
言語 | en | |||||
著者 |
Kitamura, Yuki
× Kitamura, Yuki× Murata, Yuki× Oguri, Ayaka× Matsumura, Mio× Kakusawa, Naoki× Naka, Hiroshi× Yasuike, Shuji |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | "This is the peer reviewed version of the following article: [Y. Kitamura, Y. Murata, A. Oguri, M. Matsumura, N. Kakusawa, H. Naka, S. Yasuike, Asian J. Org. Chem. 2019, 8, 138.], which has been published in final form at [https://doi.org/10.1002/ajoc.201800654]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Antimony | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Thiophene | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Palladium catalyst | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Pentavalent triarylantimony difluoride | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | β-selective C−H arylation | |||||
抄録 | ||||||
内容記述 | Regioselective C−H arylation using pentavalent organoantimony compounds as a new class of arylating reagents is described. The reaction of thiophenes with triarylantimony difluorides in the presence of 5 mol% of Pd(OAc)2 and 2 equiv. CuCl2 at 80 °C under aerobic conditions afforded the β‐arylated thiophene derivatives in moderate‐to‐high yields. The reaction is sensitive to the electronic nature of the triarylantimony difluorides – those bearing an electron‐donating group on the phenyl ring showed higher reactivity than those have an electron‐withdrawing group. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-01-01 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/ajoc.201800654 | |||||
ISSN(Online) | ||||||
収録物識別子タイプ | EISSN | |||||
収録物識別子 | 2193-5807 | |||||
書誌情報 |
en : Asian Journal of Organic Chemistry 巻 8, 号 1, p. 138-143, 発行日 2019-01 |
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著者版フラグ | ||||||
値 | author |