{"_buckets": {"deposit": "0eecf8ab-8678-43ce-9d52-26ebfd44323e"}, "_deposit": {"id": "27948", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27948"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027948"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "143", "bibliographicPageStart": "138", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{"bibliographic_title": "Asian Journal of Organic Chemistry"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Regioselective C\u2212H arylation using pentavalent organoantimony compounds as a new class of arylating reagents is described. The reaction of thiophenes with triarylantimony difluorides in the presence of 5\u2005mol% of Pd(OAc)2 and 2\u2005equiv. CuCl2 at 80\u2009\u00b0C under aerobic conditions afforded the \u03b2\u2010arylated thiophene derivatives in moderate\u2010to\u2010high yields. The reaction is sensitive to the electronic nature of the triarylantimony difluorides \u2013 those bearing an electron\u2010donating group on the phenyl ring showed higher reactivity than those have an electron\u2010withdrawing group.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-01-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ajoc.201800654", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": " \t\"This is the peer reviewed version of the following article: [Y. Kitamura, Y. Murata, A. Oguri, M. Matsumura, N. Kakusawa, H. Naka, S. Yasuike, Asian J. Org. Chem. 2019, 8, 138.], which has been published in final form at [https://doi.org/10.1002/ajoc.201800654]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "2193-5807", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kitamura, Yuki"}], "nameIdentifiers": [{"nameIdentifier": "90991", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Murata, Yuki"}], "nameIdentifiers": [{"nameIdentifier": "90992", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oguri, Ayaka"}], "nameIdentifiers": [{"nameIdentifier": "90993", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsumura, Mio"}], "nameIdentifiers": [{"nameIdentifier": "90994", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kakusawa, Naoki"}], "nameIdentifiers": [{"nameIdentifier": "90995", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Naka, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "90996", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasuike, Shuji"}], "nameIdentifiers": [{"nameIdentifier": "90997", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-01-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AJOC181113_3.pdf", "filesize": [{"value": "448.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 448400.0, "url": {"label": "AJOC181113_3", "url": "https://nagoya.repo.nii.ac.jp/record/27948/files/AJOC181113_3.pdf"}, "version_id": "0e99f951-9af7-41df-afe0-cdbdd5958df0"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Antimony", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Thiophene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Palladium catalyst", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pentavalent triarylantimony difluoride", "subitem_subject_scheme": "Other"}, {"subitem_subject": "\u03b2-selective C\u2212H arylation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Pd\u2010Catalyzed \u03b2\u2010Selective C\u2212H Arylation of Thiophenes with Triarylantimony Difluorides", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Pd\u2010Catalyzed \u03b2\u2010Selective C\u2212H Arylation of Thiophenes with Triarylantimony Difluorides"}]}, "item_type_id": "10", "owner": "1", "path": ["1917/1918/1919"], "permalink_uri": "http://hdl.handle.net/2237/00030147", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2019-05-09"}, "publish_date": "2019-05-09", "publish_status": "0", "recid": "27948", "relation": {}, "relation_version_is_last": true, "title": ["Pd\u2010Catalyzed \u03b2\u2010Selective C\u2212H Arylation of Thiophenes with Triarylantimony Difluorides"], "weko_shared_id": null}