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Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene
http://hdl.handle.net/2237/00030404
http://hdl.handle.net/2237/00030404feb81fd9-1f84-4238-8ec4-59bdd63ca533
名前 / ファイル | ライセンス | アクション |
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JOURNAL_OF_POLYMER_SCIENCE_PART_A_57_3_2019_465-473 (2.2 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-06-07 | |||||
タイトル | ||||||
タイトル | Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene | |||||
言語 | en | |||||
著者 |
Satoh, Kotaro
× Satoh, Kotaro× Mori, Yuya× Kamigaito, Masami |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [Satoh, K. , Mori, Y. and Kamigaito, M. (2019), Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene. J. Polym. Sci. Part A: Polym. Chem., 57: 465-473. doi:10.1002/pola.29261], which has been published in final form at [https://doi.org/10.1002/pola.29261]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | carbon–halogen bond | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | living anionic polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | living cationic polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | living radical polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | mechanistic transformation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | styrene | |||||
抄録 | ||||||
内容記述 | In this work, we examined the synthesis of novel block (co)polymers by mechanistic transformation through anionic, cationic, and radical living polymerizations using terminal carbon–halogen bond as the dormant species. First, the direct halogenation of growing species in the living anionic polymerization of styrene was examined with CCl4 to form a carbon–halogen terminal, which can be employed as the dormant species for either living cationic or radical polymerization. The mechanistic transformation was then performed from living anionic polymerization into living cationic or radical polymerization using the obtained polymers as the macroinitiator with the SnCl4/n‐Bu4NCl or RuCp*Cl(PPh3)/Et3N initiating system, respectively. Finally, the combination of all the polymerizations allowed the synthesis block copolymers including unprecedented gradient block copolymers composed of styrene and p‐methylstyrene. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-02-01 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/pola.29261 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0887-624X | |||||
書誌情報 |
en : Journal of Polymer Science Part A: Polymer Chemistry 巻 57, 号 3, p. 465-473, 発行日 2019-02-01 |
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著者版フラグ | ||||||
値 | author |