WEKO3
アイテム
Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3
http://hdl.handle.net/2237/00030411
http://hdl.handle.net/2237/000304119bbc0df2-adbd-4f2b-b572-5c21dacbf2da
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
manuscript20190611 (12.7 MB)
|
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-06-11 | |||||
| タイトル | ||||||
| タイトル | Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3 | |||||
| 言語 | en | |||||
| 著者 |
Horibe, Takahiro
× Horibe, Takahiro× Ohmura, Shuhei× Ishihara, Kazuaki |
|||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-KpstntDrJeZDzRJWKebU].” | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | This paper describes the isolation and characterization of an aromatic radical cation generated by FeCl3. X-ray crystallographic analysis and kinetic studies reveal the mechanism of the generation of aromatic radical cation. In the solid state, a tight ion-pair of a radical cation with FeCl4^– is observed. Leveraging the efficient generation of the radical cation–FeCl4^– ion pair, we explore a radical cation-induced cycloaddition of trans-anethole initiated by catalytic amount of FeCl3. Both [4+2] cycloaddition and [2+2] cycloaddition with a broad substrate scope are also described. Moreover, a 100 g-scale reaction is demonstrated with the use of 1 mol % of FeCl3 as a simple and a highly active initiator. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2020-02-06 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/jacs.8b12827 | |||||
| ISSN（print） | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0002-7863 | |||||
| 書誌情報 |
en : Journal of the American Chemical Society 巻 141, 号 5, p. 1877-1881, 発行日 2019-02-06 |
|||||
| 著者版フラグ | ||||||
| 値 | author | |||||
