{"_buckets": {"deposit": "c8f3b259-8fdf-4b6e-b18d-2158a2852a2d"}, "_deposit": {"id": "28501", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28501"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028501"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-05-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "9", "bibliographicPageEnd": "3341", "bibliographicPageStart": "3327", "bibliographicVolumeNumber": "52", "bibliographic_titles": [{"bibliographic_title": "Macromolecules"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A series of sequence-regulated vinyl copolymers with high-order and long vinyl monomer sequences were constructed via a combination of iterative single vinyl monomer additions, which were mediated by radical and cationic intermediates, and subsequent metal-catalyzed step-growth radical polymerization. The construction of vinyl monomer sequences was attained by iterative single monomer radical and cationic additions between a dichloride, having a similar substituent to that of vinyl monomers, and vinyl monomers such as styrenes, acrylates, and acrylonitrile. The resulting products were converted into sequence-regulated ab-type monomers that have embedded vinyl monomer sequences between an unconjugated C\u2550C bond and reactive C\u2013Cl bond via selective allylation of one of the two C\u2013Cl bonds at their terminals. The synthesized sequence-regulated ab-type monomers were polymerized via metal-catalyzed step-growth radical polymerization, which resulted in vinyl chloride units via repetitive intermolecular addition reactions between the C\u2550C and C\u2013Cl terminals. Alternatively, aa- and bb-type sequence-regulated monomers, which have two unconjugated C\u2550C and two reactive C\u2013Cl bonds, respectively, were prepared by similar iterative single monomer additions and were subsequently polymerized via metal-catalyzed step-growth radical polymerization. The repeating vinyl monomer sequence codes in the resulting polymers, such as ABCC, ABCD, ABBAC, ABDBAC, and ABDBACAEEAC, varied from 4 to 11 monomer units in which the embedded vinyl monomer units were styrenes, acrylates, acrylamides, acrylonitrile, vinyl chloride, vinylidene chloride, and ethylene.", "subitem_description_type": "Abstract"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.macromol.9b00676", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-YPWWeB4KgQ4yxA4GqzIs].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0024-9297", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Satoh, Kotaro"}], "nameIdentifiers": [{"nameIdentifier": "93478", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishizuka, Kenta"}], "nameIdentifiers": [{"nameIdentifier": "93479", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hamada, Tsuyoshi"}], "nameIdentifiers": [{"nameIdentifier": "93480", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Handa, Masato"}], "nameIdentifiers": [{"nameIdentifier": "93481", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe, Tomohiro"}], "nameIdentifiers": [{"nameIdentifier": "93482", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ozawa, Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "93483", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyajima, Masato"}], "nameIdentifiers": [{"nameIdentifier": "93484", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamigaito, Masami"}], "nameIdentifiers": [{"nameIdentifier": "93485", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-05-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "MACROMOLECULES_52_9_2019_3327-3341.pdf", "filesize": [{"value": "1.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1900000.0, "url": {"label": "MACROMOLECULES_52_9_2019_3327-3341", "url": "https://nagoya.repo.nii.ac.jp/record/28501/files/MACROMOLECULES_52_9_2019_3327-3341.pdf"}, "version_id": "0f9e86ee-5e31-444b-bc28-2b5e09800819"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00030692", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2019-09-17"}, "publish_date": "2019-09-17", "publish_status": "0", "recid": "28501", "relation": {}, "relation_version_is_last": true, "title": ["Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization"], "weko_shared_id": null}