ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization

http://hdl.handle.net/2237/00030692
http://hdl.handle.net/2237/00030692
97021deb-1231-4bd3-811d-6b702f082f1a
名前 / ファイル ライセンス アクション
MACROMOLECULES_52_9_2019_3327-3341.pdf MACROMOLECULES_52_9_2019_3327-3341 (1.9 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-09-17
タイトル
タイトル Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization
言語 en
著者 Satoh, Kotaro

× Satoh, Kotaro

WEKO 93478

en Satoh, Kotaro

Search repository
Ishizuka, Kenta

× Ishizuka, Kenta

WEKO 93479

en Ishizuka, Kenta

Search repository
Hamada, Tsuyoshi

× Hamada, Tsuyoshi

WEKO 93480

en Hamada, Tsuyoshi

Search repository
Handa, Masato

× Handa, Masato

WEKO 93481

en Handa, Masato

Search repository
Abe, Tomohiro

× Abe, Tomohiro

WEKO 93482

en Abe, Tomohiro

Search repository
Ozawa, Satoshi

× Ozawa, Satoshi

WEKO 93483

en Ozawa, Satoshi

Search repository
Miyajima, Masato

× Miyajima, Masato

WEKO 93484

en Miyajima, Masato

Search repository
Kamigaito, Masami

× Kamigaito, Masami

WEKO 93485

en Kamigaito, Masami

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-YPWWeB4KgQ4yxA4GqzIs].”
抄録
内容記述タイプ Abstract
内容記述 A series of sequence-regulated vinyl copolymers with high-order and long vinyl monomer sequences were constructed via a combination of iterative single vinyl monomer additions, which were mediated by radical and cationic intermediates, and subsequent metal-catalyzed step-growth radical polymerization. The construction of vinyl monomer sequences was attained by iterative single monomer radical and cationic additions between a dichloride, having a similar substituent to that of vinyl monomers, and vinyl monomers such as styrenes, acrylates, and acrylonitrile. The resulting products were converted into sequence-regulated ab-type monomers that have embedded vinyl monomer sequences between an unconjugated C═C bond and reactive C–Cl bond via selective allylation of one of the two C–Cl bonds at their terminals. The synthesized sequence-regulated ab-type monomers were polymerized via metal-catalyzed step-growth radical polymerization, which resulted in vinyl chloride units via repetitive intermolecular addition reactions between the C═C and C–Cl terminals. Alternatively, aa- and bb-type sequence-regulated monomers, which have two unconjugated C═C and two reactive C–Cl bonds, respectively, were prepared by similar iterative single monomer additions and were subsequently polymerized via metal-catalyzed step-growth radical polymerization. The repeating vinyl monomer sequence codes in the resulting polymers, such as ABCC, ABCD, ABBAC, ABDBAC, and ABDBACAEEAC, varied from 4 to 11 monomer units in which the embedded vinyl monomer units were styrenes, acrylates, acrylamides, acrylonitrile, vinyl chloride, vinylidene chloride, and ethylene.
言語 en
出版者
出版者 ACS Publications
言語 en
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.macromol.9b00676
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0024-9297
書誌情報 en : Macromolecules

巻 52, 号 9, p. 3327-3341, 発行日 2019-05-14
著者版フラグ
値 author
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 09:59:59.686018
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR 2.0
  • OAI-PMH JPCOAR 1.0
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3