{"_buckets": {"deposit": "c8f3b259-8fdf-4b6e-b18d-2158a2852a2d"}, "_deposit": {"id": "28501", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28501"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028501", "sets": ["322"]}, "author_link": ["93478", "93479", "93480", "93481", "93482", "93483", "93484", "93485"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-05-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "9", "bibliographicPageEnd": "3341", "bibliographicPageStart": "3327", "bibliographicVolumeNumber": "52", "bibliographic_titles": [{"bibliographic_title": "Macromolecules", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A series of sequence-regulated vinyl copolymers with high-order and long vinyl monomer sequences were constructed via a combination of iterative single vinyl monomer additions, which were mediated by radical and cationic intermediates, and subsequent metal-catalyzed step-growth radical polymerization. The construction of vinyl monomer sequences was attained by iterative single monomer radical and cationic additions between a dichloride, having a similar substituent to that of vinyl monomers, and vinyl monomers such as styrenes, acrylates, and acrylonitrile. The resulting products were converted into sequence-regulated ab-type monomers that have embedded vinyl monomer sequences between an unconjugated C═C bond and reactive C–Cl bond via selective allylation of one of the two C–Cl bonds at their terminals. The synthesized sequence-regulated ab-type monomers were polymerized via metal-catalyzed step-growth radical polymerization, which resulted in vinyl chloride units via repetitive intermolecular addition reactions between the C═C and C–Cl terminals. Alternatively, aa- and bb-type sequence-regulated monomers, which have two unconjugated C═C and two reactive C–Cl bonds, respectively, were prepared by similar iterative single monomer additions and were subsequently polymerized via metal-catalyzed step-growth radical polymerization. The repeating vinyl monomer sequence codes in the resulting polymers, such as ABCC, ABCD, ABBAC, ABDBAC, and ABDBACAEEAC, varied from 4 to 11 monomer units in which the embedded vinyl monomer units were styrenes, acrylates, acrylamides, acrylonitrile, vinyl chloride, vinylidene chloride, and ethylene.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.macromol.9b00676", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-YPWWeB4KgQ4yxA4GqzIs].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "0024-9297", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Satoh, Kotaro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93478", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishizuka, Kenta", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93479", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hamada, Tsuyoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93480", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Handa, Masato", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93481", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe, Tomohiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93482", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ozawa, Satoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93483", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyajima, Masato", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93484", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamigaito, Masami", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "93485", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-05-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "MACROMOLECULES_52_9_2019_3327-3341.pdf", "filesize": [{"value": "1.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1900000.0, "url": {"label": "MACROMOLECULES_52_9_2019_3327-3341", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/28501/files/MACROMOLECULES_52_9_2019_3327-3341.pdf"}, "version_id": "0f9e86ee-5e31-444b-bc28-2b5e09800819"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00030692", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-09-17"}, "publish_date": "2019-09-17", "publish_status": "0", "recid": "28501", "relation": {}, "relation_version_is_last": true, "title": ["Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization"], "weko_shared_id": -1}