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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Synthesis of meso-Alkyl-Substituted Norcorrole–Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)

http://hdl.handle.net/2237/00030812
http://hdl.handle.net/2237/00030812
4884501b-48d8-4c48-bd7d-8397d00fdaea
名前 / ファイル ライセンス アクション
alkyl_norcorrole0419.pdf alkyl_norcorrole0419 (2.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-10-16
タイトル
タイトル Synthesis of meso-Alkyl-Substituted Norcorrole–Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)
言語 en
著者 Liu, Si‐Yu

× Liu, Si‐Yu

WEKO 93717

en Liu, Si‐Yu

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Tanaka, Hiroko

× Tanaka, Hiroko

WEKO 93718

en Tanaka, Hiroko

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Nozawa, Ryo

× Nozawa, Ryo

WEKO 93719

en Nozawa, Ryo

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Fukui, Norihito

× Fukui, Norihito

WEKO 93720

en Fukui, Norihito

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Shinokubo, Hiroshi

× Shinokubo, Hiroshi

WEKO 93721

en Shinokubo, Hiroshi

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [S.-Y. Liu, H. Tanaka, R. Nozawa, N. Fukui, H. Shinokubo, Chem. Eur. J. 2019, 25, 7618.], which has been published in final form at [https://doi.org/10.1002/chem.201901292]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
抄録
内容記述 The synthesis of antiaromatic Ni^II–norcorroles having primary, secondary, and tertiary alkyl groups at the reactive meso‐positions was attempted. Reductive coupling of a Ni^II–dipyrrin precursor provided Ni^II–meso‐dihexylnorcorrole, which underwent substantial degradation on silica gel. Introduction of tert‐butyl groups was unsuccessful due to the difficult preparation of the corresponding dipyrrin precursor. Meanwhile, Ni^II–norcorroles with isopropyl and cyclohexyl groups were isolated as stable molecules under ambient conditions. Furthermore, we found that oxidation of Ni^II–meso‐dialkylnorcorroles with hydrogen peroxide in the presence of sodium carbonate gave Ni^II–5‐oxaporphyrins(2.0.1.0). In contrast, oxidation of Ni^II–meso‐dimesitylnorcorrole under the same reaction conditions gave 10‐oxaporphyrin(1.1.1.0). The contrasting reactivity can be attributed to the steric congestion around the meso‐positions.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-06-07
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201901292
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0947-6539
書誌情報 en : Chemistry – A European Journal

巻 25, 号 32, p. 7618-7622, 発行日 2019-06-07
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