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Synthesis of meso-Alkyl-Substituted Norcorrole–Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)
http://hdl.handle.net/2237/00030812
4884501b-48d8-4c48-bd7d-8397d00fdaea
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-10-16 | |||||
タイトル | ||||||
タイトル | Synthesis of meso-Alkyl-Substituted Norcorrole–Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0) | |||||
著者 |
Liu, Si‐Yu
× Liu, Si‐Yu× Tanaka, Hiroko× Nozawa, Ryo× Fukui, Norihito× Shinokubo, Hiroshi |
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権利 | ||||||
権利情報 | "This is the peer reviewed version of the following article: [S.-Y. Liu, H. Tanaka, R. Nozawa, N. Fukui, H. Shinokubo, Chem. Eur. J. 2019, 25, 7618.], which has been published in final form at [https://doi.org/10.1002/chem.201901292]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | |||||
抄録 | ||||||
内容記述 | The synthesis of antiaromatic Ni^II–norcorroles having primary, secondary, and tertiary alkyl groups at the reactive meso‐positions was attempted. Reductive coupling of a Ni^II–dipyrrin precursor provided Ni^II–meso‐dihexylnorcorrole, which underwent substantial degradation on silica gel. Introduction of tert‐butyl groups was unsuccessful due to the difficult preparation of the corresponding dipyrrin precursor. Meanwhile, Ni^II–norcorroles with isopropyl and cyclohexyl groups were isolated as stable molecules under ambient conditions. Furthermore, we found that oxidation of Ni^II–meso‐dialkylnorcorroles with hydrogen peroxide in the presence of sodium carbonate gave Ni^II–5‐oxaporphyrins(2.0.1.0). In contrast, oxidation of Ni^II–meso‐dimesitylnorcorrole under the same reaction conditions gave 10‐oxaporphyrin(1.1.1.0). The contrasting reactivity can be attributed to the steric congestion around the meso‐positions. | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-06-07 | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/chem.201901292 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0947-6539 | |||||
書誌情報 |
Chemistry – A European Journal 巻 25, 号 32, p. 7618-7622, 発行日 2019-06-07 |
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著者版フラグ | ||||||
値 | author |