{"_buckets": {"deposit": "e3d9f2b2-75ec-4fbc-8ba2-5f2f97ae2218"}, "_deposit": {"id": "28622", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28622"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028622"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-06-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "32", "bibliographicPageEnd": "7622", "bibliographicPageStart": "7618", "bibliographicVolumeNumber": "25", "bibliographic_titles": [{"bibliographic_title": "Chemistry \u2013 A European Journal"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The synthesis of antiaromatic Ni^II\u2013norcorroles having primary, secondary, and tertiary alkyl groups at the reactive meso\u2010positions was attempted. Reductive coupling of a Ni^II\u2013dipyrrin precursor provided Ni^II\u2013meso\u2010dihexylnorcorrole, which underwent substantial degradation on silica gel. Introduction of tert\u2010butyl groups was unsuccessful due to the difficult preparation of the corresponding dipyrrin precursor. Meanwhile, Ni^II\u2013norcorroles with isopropyl and cyclohexyl groups were isolated as stable molecules under ambient conditions. Furthermore, we found that oxidation of Ni^II\u2013meso\u2010dialkylnorcorroles with hydrogen peroxide in the presence of sodium carbonate gave Ni^II\u20135\u2010oxaporphyrins(2.0.1.0). In contrast, oxidation of Ni^II\u2013meso\u2010dimesitylnorcorrole under the same reaction conditions gave 10\u2010oxaporphyrin(1.1.1.0). The contrasting reactivity can be attributed to the steric congestion around the meso\u2010positions.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-06-07", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201901292", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [S.-Y. Liu, H. Tanaka, R. Nozawa, N. Fukui, H. Shinokubo, Chem. Eur. J. 2019, 25, 7618.], which has been published in final form at [https://doi.org/10.1002/chem.201901292]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Liu, Si\u2010Yu"}], "nameIdentifiers": [{"nameIdentifier": "93717", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanaka, Hiroko"}], "nameIdentifiers": [{"nameIdentifier": "93718", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nozawa, Ryo"}], "nameIdentifiers": [{"nameIdentifier": "93719", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukui, Norihito"}], "nameIdentifiers": [{"nameIdentifier": "93720", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "93721", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-06-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "alkyl_norcorrole0419.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "alkyl_norcorrole0419", "url": "https://nagoya.repo.nii.ac.jp/record/28622/files/alkyl_norcorrole0419.pdf"}, "version_id": "52287baf-0ed7-4c95-a9b2-5b133fde438e"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00030812", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2019-10-16"}, "publish_date": "2019-10-16", "publish_status": "0", "recid": "28622", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)"], "weko_shared_id": null}