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Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position
http://hdl.handle.net/2237/00030870
http://hdl.handle.net/2237/0003087036cae49b-2120-4110-9566-38d8ca64ab50
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Bcorrole_revised (2.4 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-11-13 | |||||
| タイトル | ||||||
| タイトル | Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position | |||||
| 言語 | en | |||||
| 著者 |
Omori, Hiroto
× Omori, Hiroto× Shinokubo, Hiroshi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-S9f4xWKW8p566Ss4DYjy].” | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A Ni(II) 10-boracorrole (2) was obtained from the transmetalation of the corresponding 10-silacorrole with BBr3. The antiaromaticity of 2 was examined by 1H NMR spectroscopy and theoretical calculations. The antiaromatic character of 2 is reflected in a very narrow HOMO–LUMO gap that results in weak and broad absorption bands in the NIR region up to 1800 nm. Furthermore, titration experiments revealed a high Lewis acidity of 2 toward pyridines. Theoretical calculations on 2 indicated the presence of p−π^* conjugation, which significantly stabilizes the energy level of its LUMO. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2020-08-12 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/acs.organomet.9b00303 | |||||
| ISSN（print） | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0276-7333 | |||||
| 書誌情報 |
en : Organometallics 巻 38, 号 15, p. 2878-2882, 発行日 2019-08-12 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
