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Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes
http://hdl.handle.net/2237/00031175
http://hdl.handle.net/2237/00031175605f36b0-ef1a-4d18-989d-d5e2350196e4
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-01-15 | |||||
タイトル | ||||||
タイトル | Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes | |||||
言語 | en | |||||
著者 |
Ariyasu, Shinya
× Ariyasu, Shinya× Kodama, Yusaku× Kasai, Chie× Cong, Zhiqi× Stanfield, Joshua Kyle× Aiba, Yuichiro× Watanabe, Yoshihito× Shoji, Osami |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [S. Ariyasu, Y. Kodama, C. Kasai, Z. Cong, J. K. Stanfield, Y. Aiba, Y. Watanabe, O. Shoji, ChemCatChem 2019, 11, 4709.], which has been published in final form at [https://doi.org/10.1002/cctc.201901323]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | high pressure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cytochrome P450 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydroxylation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ethane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | propane | |||||
抄録 | ||||||
内容記述 | A new type of high‐pressure reactor based on liquid‐flow pressurisation using a HPLC pump has been developed. This high‐pressure reactor allows the easy and safe performance of reactions with gaseous alkanes under high‐pressures up to 10 MPa (100 atm), without the need for high‐pressure gas cylinders. The amount of substrate gas required for a single reaction is very small compared with reactions using a conventional autoclave, which, when using expensive substrate gasses, such as 13C‐labelled ethane, becomes critical. Employing this high‐pressure reactor in conjunction with cytochrome P450BM3 and the assistance of decoy molecules, the direct hydroxylation of gaseous alkanes was drastically improved. At 5 MPa the TOF of propane hydroxylation increased 10‐fold, reaching 2200 min^−1. Hydroxylation of ethane was also substantially accelerated at 5 MPa, reaching a TOF of 28 min^−1. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-10-07 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/cctc.201901323 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1867-3880 | |||||
書誌情報 |
en : ChemCatChem 巻 11, 号 19, p. 4709-4714, 発行日 2019-10-07 |
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著者版フラグ | ||||||
値 | author |