{"_buckets": {"deposit": "414c052b-e1d1-4df3-9240-a4f393ceb369"}, "_deposit": {"id": "28988", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28988"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028988"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "19", "bibliographicPageEnd": "4714", "bibliographicPageStart": "4709", "bibliographicVolumeNumber": "11", "bibliographic_titles": [{"bibliographic_title": "ChemCatChem"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A new type of high\u2010pressure reactor based on liquid\u2010flow pressurisation using a HPLC pump has been developed. This high\u2010pressure reactor allows the easy and safe performance of reactions with gaseous alkanes under high\u2010pressures up to 10\u2005MPa (100\u2005atm), without the need for high\u2010pressure gas cylinders. The amount of substrate gas required for a single reaction is very small compared with reactions using a conventional autoclave, which, when using expensive substrate gasses, such as 13C\u2010labelled ethane, becomes critical. Employing this high\u2010pressure reactor in conjunction with cytochrome P450BM3 and the assistance of decoy molecules, the direct hydroxylation of gaseous alkanes was drastically improved. At 5\u2005MPa the TOF of propane hydroxylation increased 10\u2010fold, reaching 2200\u2005min^\u22121. Hydroxylation of ethane was also substantially accelerated at 5\u2005MPa, reaching a TOF of 28\u2005min^\u22121.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-10-07", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/cctc.201901323", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [S. Ariyasu, Y. Kodama, C. Kasai, Z. Cong, J. K. Stanfield, Y. Aiba, Y. Watanabe, O. Shoji, ChemCatChem 2019, 11, 4709.], which has been published in final form at [https://doi.org/10.1002/cctc.201901323]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1867-3880", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ariyasu, Shinya"}], "nameIdentifiers": [{"nameIdentifier": "95206", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kodama, Yusaku"}], "nameIdentifiers": [{"nameIdentifier": "95207", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kasai, Chie"}], "nameIdentifiers": [{"nameIdentifier": "95208", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Cong, Zhiqi"}], "nameIdentifiers": [{"nameIdentifier": "95209", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Stanfield, Joshua Kyle"}], "nameIdentifiers": [{"nameIdentifier": "95210", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Aiba, Yuichiro"}], "nameIdentifiers": [{"nameIdentifier": "95211", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Watanabe, Yoshihito"}], "nameIdentifiers": [{"nameIdentifier": "95212", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shoji, Osami"}], "nameIdentifiers": [{"nameIdentifier": "95213", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-10-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715.pdf", "filesize": [{"value": "662.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 662200.0, "url": {"label": "Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715", "url": "https://nagoya.repo.nii.ac.jp/record/28988/files/Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715.pdf"}, "version_id": "c07b128f-b4cb-4b49-b690-e75ecb5cc5c8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "high pressure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cytochrome P450", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroxylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ethane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "propane", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Development of a High\u2010Pressure Reactor Based on Liquid\u2010Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Development of a High\u2010Pressure Reactor Based on Liquid\u2010Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/00031175", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-01-15"}, "publish_date": "2020-01-15", "publish_status": "0", "recid": "28988", "relation": {}, "relation_version_is_last": true, "title": ["Development of a High\u2010Pressure Reactor Based on Liquid\u2010Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes"], "weko_shared_id": null}