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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes

http://hdl.handle.net/2237/00031175
605f36b0-ef1a-4d18-989d-d5e2350196e4
名前 / ファイル ライセンス アクション
Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715.pdf Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715 (662.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-01-15
タイトル
タイトル Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes
著者 Ariyasu, Shinya

× Ariyasu, Shinya

WEKO 95206

Ariyasu, Shinya

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Kodama, Yusaku

× Kodama, Yusaku

WEKO 95207

Kodama, Yusaku

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Kasai, Chie

× Kasai, Chie

WEKO 95208

Kasai, Chie

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Cong, Zhiqi

× Cong, Zhiqi

WEKO 95209

Cong, Zhiqi

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Stanfield, Joshua Kyle

× Stanfield, Joshua Kyle

WEKO 95210

Stanfield, Joshua Kyle

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Aiba, Yuichiro

× Aiba, Yuichiro

WEKO 95211

Aiba, Yuichiro

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Watanabe, Yoshihito

× Watanabe, Yoshihito

WEKO 95212

Watanabe, Yoshihito

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Shoji, Osami

× Shoji, Osami

WEKO 95213

Shoji, Osami

Search repository
権利
権利情報 "This is the peer reviewed version of the following article: [S. Ariyasu, Y. Kodama, C. Kasai, Z. Cong, J. K. Stanfield, Y. Aiba, Y. Watanabe, O. Shoji, ChemCatChem 2019, 11, 4709.], which has been published in final form at [https://doi.org/10.1002/cctc.201901323]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."
キーワード
主題Scheme Other
主題 high pressure
キーワード
主題Scheme Other
主題 cytochrome P450
キーワード
主題Scheme Other
主題 hydroxylation
キーワード
主題Scheme Other
主題 ethane
キーワード
主題Scheme Other
主題 propane
抄録
内容記述 A new type of high‐pressure reactor based on liquid‐flow pressurisation using a HPLC pump has been developed. This high‐pressure reactor allows the easy and safe performance of reactions with gaseous alkanes under high‐pressures up to 10 MPa (100 atm), without the need for high‐pressure gas cylinders. The amount of substrate gas required for a single reaction is very small compared with reactions using a conventional autoclave, which, when using expensive substrate gasses, such as 13C‐labelled ethane, becomes critical. Employing this high‐pressure reactor in conjunction with cytochrome P450BM3 and the assistance of decoy molecules, the direct hydroxylation of gaseous alkanes was drastically improved. At 5 MPa the TOF of propane hydroxylation increased 10‐fold, reaching 2200 min^−1. Hydroxylation of ethane was also substantially accelerated at 5 MPa, reaching a TOF of 28 min^−1.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-10-07
内容記述タイプ Other
出版者
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/cctc.201901323
ISSN(print)
収録物識別子タイプ ISSN
収録物識別子 1867-3880
書誌情報 ChemCatChem

巻 11, 号 19, p. 4709-4714, 発行日 2019-10-07
著者版フラグ
値 author
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