{"_buckets": {"deposit": "34130c47-8dad-4318-8d19-ebc4f9c76aa3"}, "_deposit": {"id": "29316", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "29316"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00029316"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10-23", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "42", "bibliographicPageEnd": "16558", "bibliographicPageStart": "16553", "bibliographicVolumeNumber": "141", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "High efficiency perovskite solar cells have underpinned the rapid growth of the field. However, their low device stability limits further advancement. Hygroscopic lithium bis(trifluoromethanesulfonyl)imide (Li^+TFSI^\u2013) and metal electrode are the main causes of the device instability. In this work, the redox reaction between lithium-ion endohedral fullerenes and 2,2\u2032,7,7\u2032-tetrakis(N,N-di-p-methoxyphenylamine)-9,9\u2032-spirobi-fluorene (spiro-MeOTAD) was controlled to optimize the amount of oxidized spiro-MeOTAD and antioxidizing neutral endohedral fullerenes. Application of this mixture to metal-free carbon nanotube (CNT)-laminated perovskite solar cells resulted in 17.2% efficiency with a stability time of more than 1100 h under severe conditions (temperature = 60 \u00b0C, humidity = 70%). Such high performance is attributed to the uninhibited charge flow, no metal-ion migration, and the enhanced antioxidizing activity of the devices.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-10-23", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.9b06418", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-xJzrWDW3Dsxtz4c5gPGA].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Jeon, Il"}], "nameIdentifiers": [{"nameIdentifier": "96000", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shawky, Ahmed"}], "nameIdentifiers": [{"nameIdentifier": "96001", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lin, Hao-Sheng"}], "nameIdentifiers": [{"nameIdentifier": "96002", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Seo, Seungju"}], "nameIdentifiers": [{"nameIdentifier": "96003", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "96004", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lee, Jin-Wook"}], "nameIdentifiers": [{"nameIdentifier": "96005", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Pal, Amrita"}], "nameIdentifiers": [{"nameIdentifier": "96006", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tan, Shaun"}], "nameIdentifiers": [{"nameIdentifier": "96007", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Anisimov, Anton"}], "nameIdentifiers": [{"nameIdentifier": "96008", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kauppinen, Esko I."}], "nameIdentifiers": [{"nameIdentifier": "96009", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yang, Yang"}], "nameIdentifiers": [{"nameIdentifier": "96010", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Manzhos, Sergei"}], "nameIdentifiers": [{"nameIdentifier": "96011", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Shigeo"}], "nameIdentifiers": [{"nameIdentifier": "96012", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Yutaka"}], "nameIdentifiers": [{"nameIdentifier": "96013", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-10-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "LiC60TFSI CNT MS JACS revised 2.pdf", "filesize": [{"value": "4.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 4400000.0, "url": {"label": "LiC60TFSI CNT MS JACS revised 2", "url": "https://nagoya.repo.nii.ac.jp/record/29316/files/LiC60TFSI CNT MS JACS revised 2.pdf"}, "version_id": "f941dbb9-2cd2-403a-bb41-48938eac4f31"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Endohedral Fullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Metallofullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Carbon Nanotube", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Perovskite Solar Cells", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Stability of Solar Cells", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells"}]}, "item_type_id": "10", "owner": "1", "path": ["1939/1940/1941"], "permalink_uri": "http://hdl.handle.net/2237/00031503", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-02-13"}, "publish_date": "2020-02-13", "publish_status": "0", "recid": "29316", "relation": {}, "relation_version_is_last": true, "title": ["Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells"], "weko_shared_id": null}