{"_buckets": {"deposit": "a241dce6-6e8e-4df0-be27-e14a17469ebd"}, "_deposit": {"id": "30135", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30135"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030135", "sets": ["322"]}, "author_link": ["99471", "99472", "99473", "99474"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "01n03", "bibliographicPageEnd": "89", "bibliographicPageStart": "84", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "Journal of Porphyrins and Phthalocyanines", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We have successfully prepared 5-aza-15-thiaporphyrin through nucleophilic sulfination of nitrogen-bridged dibromobisdipyrrin with sodium sulfide. X-ray diffraction analysis elucidated its structure in the solid state: two dipyrrin subunits were roughly coplanar around the sp^2-hybridized meso-nitrogen. In contrast, they adopted a folded conformation around the meso-sulfur atom. Due to its relatively distorted structure, 5-aza-15-thiaporphyrin shows weak antiaromaticity in the magnetic criteria. The sulfur atom was oxidized with m-chloroperbenzoic acid to provide 5-aza-15-thiaporphyrin S-dioxide in good yield. While 5-aza-15-thiaporphyrin was non-emissive, its S-dioxide exhibited fluorescence in solution.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2021/03/01", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "World Scientific", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1142/S108842461950069X", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Electronic version of an article published as [Journal of Porphyrins and Phthalocyanines. v.24, n.01n03, 2020, p.84-89] [http://doi.org/10.1142/S108842461950069X] © [copyright World Scientific Publishing Company] [https://www.worldscientific.com/worldscinet/jpp]", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "1088-4246", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamashita, Daisuke", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99471", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Omori, Hiroto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99472", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukui, Norihito", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99473", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99474", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-03-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "shinokubo_man-revised.pdf", "filesize": [{"value": "3.0 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 3000000.0, "url": {"label": "shinokubo_man-revised", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/30135/files/shinokubo_man-revised.pdf"}, "version_id": "18f2d381-1198-4662-8a9e-7baaca10eb2b"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "5-aza-15-thiaporphyrin", "subitem_subject_scheme": "Other"}, {"subitem_subject": "antiaromaticity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "heteroporphyrinoids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "sulfide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "sulfone", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis and properties of 5-aza-15-thiaporphyrins", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis and properties of 5-aza-15-thiaporphyrins", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00032321", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-06-09"}, "publish_date": "2020-06-09", "publish_status": "0", "recid": "30135", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis and properties of 5-aza-15-thiaporphyrins"], "weko_shared_id": -1}