{"_buckets": {"deposit": "c4a8ea16-cfbb-4d1f-b668-3c7e59d8471e"}, "_deposit": {"id": "30136", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30136"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030136"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-12-18", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "50", "bibliographicPageEnd": "19816", "bibliographicPageStart": "19807", "bibliographicVolumeNumber": "141", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Establishing design principles to create nonplanar \u03c0-conjugated molecules is crucial for the development of novel functional materials. Herein, we describe the synthesis and properties of dinaphtho[1,8-bc:1\u2032,8\u2032-ef]azepine bisimides (DNABIs). Their molecular design is conceptually based on the insertion of a nitrogen atom into a perylene bisimide core. We have synthesized several DNABI derivatives with a hydrogen atom, a primary alkyl group, or an aryl group on the central nitrogen atom. These DNABIs exhibit nonplanar conformations, flexible structural changes, and ambipolar redox activity. The steric effect around the central nitrogen atom substantially affects the overall structures and results in two different conformations: a nonsymmetric bent conformation and a symmetric twisted conformation, accompanied by a drastic change in electronic properties. Notably, the nonsymmetric DNABI undergoes unique structural changes in response to the application of an external electric field, which is due to molecular motions that are accompanied by an orientational fluctuation of the dipole moment. Furthermore, the addition of a chiral Br\u00f8nsted base to N-unsubstituted DNABI affords control over the helical chirality via hydrogen-bonding interactions.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-12-18", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.9b09556", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-5dRwd4tC3PMYHdj35yp5].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hayakawa, Sakiho"}], "nameIdentifiers": [{"nameIdentifier": "99475", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawasaki, Ayumi"}], "nameIdentifiers": [{"nameIdentifier": "99476", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hong, Yongseok"}], "nameIdentifiers": [{"nameIdentifier": "99477", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uraguchi, Daisuke"}], "nameIdentifiers": [{"nameIdentifier": "99478", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ooi, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "99479", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Dongho"}], "nameIdentifiers": [{"nameIdentifier": "99480", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Akutagawa, Tomoyuki"}], "nameIdentifiers": [{"nameIdentifier": "99481", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukui, Norihito"}], "nameIdentifiers": [{"nameIdentifier": "99482", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "99483", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-12-18"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "N-PBI_rev.pdf", "filesize": [{"value": "3.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 3900000.0, "url": {"label": "N-PBI_rev", "url": "https://nagoya.repo.nii.ac.jp/record/30136/files/N-PBI_rev.pdf"}, "version_id": "7ebe6db7-36cc-41b3-b484-20a079ab98cf"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032322", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-06-09"}, "publish_date": "2020-06-09", "publish_status": "0", "recid": "30136", "relation": {}, "relation_version_is_last": true, "title": ["Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues"], "weko_shared_id": null}