{"_buckets": {"deposit": "1c6603b9-1446-4074-9b73-09a5ea26cf3d"}, "_deposit": {"id": "30144", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30144"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030144"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-02-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "387", "bibliographicPageStart": "383", "bibliographicVolumeNumber": "39", "bibliographic_titles": [{"bibliographic_title": "Organometallics"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Reactions of boron- and nitrogen-substituted acetylene toward hydro-/chloroboranes are described. The X-ray crystallography revealed the formation of BCBH/BCBCl four-membered rings in the solid state. By NMR and IR spectroscopic analysis, the BCBH four-membered ring was retained even in the solution. In contrast, the BCBCl four-membered ring exists as an association/dissociation equilibrium mixture in solution. The B\u2013H\u2013B moiety forms a three-center-two-electron bond through a spherical 1s orbital of a hydrogen atom; therefore, the four-membered ring does not have significant strain. On the other hand, due to the weak coordination bond from Cl to B, the BCBCl four-membered ring was labile. In addition, the rearrangement of the BCBH ring under heating conditions is described.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-02-10", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.organomet.9b00876", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-wR8MIvpG8vJuy3xUTpUS].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0276-7333", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kobayashi, Akemi"}], "nameIdentifiers": [{"nameIdentifier": "99507", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzuki, Katsunori"}], "nameIdentifiers": [{"nameIdentifier": "99508", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kitamura, Ryo"}], "nameIdentifiers": [{"nameIdentifier": "99509", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "99510", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-02-10"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "om-2019-00876nR1_marked_revised_200123.pdf", "filesize": [{"value": "490.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 490700.0, "url": {"label": "om-2019-00876nR1_marked_revised_200123", "url": "https://nagoya.repo.nii.ac.jp/record/30144/files/om-2019-00876nR1_marked_revised_200123.pdf"}, "version_id": "a276e408-21c5-49d6-b259-05fade509e67"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032330", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-06-10"}, "publish_date": "2020-06-10", "publish_status": "0", "recid": "30144", "relation": {}, "relation_version_is_last": true, "title": ["Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes"], "weko_shared_id": null}