{"_buckets": {"deposit": "834e6ea3-5195-4da3-9cde-1f5bbbf3b630"}, "_deposit": {"id": "30328", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30328"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030328"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "100", "bibliographicPageStart": "91", "bibliographicVolumeNumber": "58", "bibliographic_titles": [{"bibliographic_title": "Journal of Polymer Science"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A series of bio\u2010based vinylphenols or hydroxystyrenes is prepared by simple decarboxylation of various naturally occurring cinnamic acids such as o\u2010, m\u2010, and p\u2010coumaric; caffeic; ferulic; and sinapinic acids, which possess hydroxy groups and other substituents at different positions on the aromatic ring. After protection of the phenolic moieties with trialkylsilyl groups, reversible addition\u2013fragmentation chain\u2010transfer polymerization is accomplished with cumyl dithiobenzoate to afford various bio\u2010based hydroxyl\u2010protected polystyrenes with controlled molecular weights and narrow molecular weight distributions. Subsequent deprotection of the silyl groups under mild conditions results in a series of well\u2010defined functionalized polystyrenes possessing different numbers (mono\u2010, di\u2010, tri\u2010) of hydroxy groups at different positions (o , m , p ). The obtained functionalized polystyrenes show unique thermal properties depending on the substituents, and those with phenol and catechol groups serve as reducing agents for silver ions.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-01-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/pola.29453", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Takeshima, H., Satoh, K. and Kamigaito, M. (2020), Bio\u2010based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes. J. Polym. Sci., 58: 91-100. doi:10.1002/pola.29453], which has been published in final form at [https://doi.org/10.1002/pola.29453]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "2642-4150", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takeshima, Hisaaki"}], "nameIdentifiers": [{"nameIdentifier": "100610", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Satoh, Kotaro"}], "nameIdentifiers": [{"nameIdentifier": "100611", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamigaito, Masami"}], "nameIdentifiers": [{"nameIdentifier": "100612", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-01-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100", "url": "https://nagoya.repo.nii.ac.jp/record/30328/files/JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100.pdf"}, "version_id": "707cfe1c-fb45-486d-a6a7-f3ea9e2a30bb"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "bio\u2010based polymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cinnamic acid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroxystyrene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "catechol", "subitem_subject_scheme": "Other"}, {"subitem_subject": "functionalization of polymers", "subitem_subject_scheme": "Other"}, {"subitem_subject": "gallol", "subitem_subject_scheme": "Other"}, {"subitem_subject": "guaiacol", "subitem_subject_scheme": "Other"}, {"subitem_subject": "living polymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "phenol", "subitem_subject_scheme": "Other"}, {"subitem_subject": "RAFT", "subitem_subject_scheme": "Other"}, {"subitem_subject": "radical polymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "syringol", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Bio\u2010based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Bio\u2010based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032514", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-07-15"}, "publish_date": "2020-07-15", "publish_status": "0", "recid": "30328", "relation": {}, "relation_version_is_last": true, "title": ["Bio\u2010based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes"], "weko_shared_id": null}