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Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes
http://hdl.handle.net/2237/00032514
http://hdl.handle.net/2237/00032514c811a974-343f-4974-af8a-c110c9312bf1
名前 / ファイル | ライセンス | アクション |
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JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100 (2.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-07-15 | |||||
タイトル | ||||||
タイトル | Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes | |||||
言語 | en | |||||
著者 |
Takeshima, Hisaaki
× Takeshima, Hisaaki× Satoh, Kotaro× Kamigaito, Masami |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [Takeshima, H., Satoh, K. and Kamigaito, M. (2020), Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes. J. Polym. Sci., 58: 91-100. doi:10.1002/pola.29453], which has been published in final form at [https://doi.org/10.1002/pola.29453]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | bio‐based polymer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cinnamic acid | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydroxystyrene | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | catechol | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | functionalization of polymers | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | gallol | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | guaiacol | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | living polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | phenol | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | RAFT | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | radical polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | syringol | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A series of bio‐based vinylphenols or hydroxystyrenes is prepared by simple decarboxylation of various naturally occurring cinnamic acids such as o‐, m‐, and p‐coumaric; caffeic; ferulic; and sinapinic acids, which possess hydroxy groups and other substituents at different positions on the aromatic ring. After protection of the phenolic moieties with trialkylsilyl groups, reversible addition–fragmentation chain‐transfer polymerization is accomplished with cumyl dithiobenzoate to afford various bio‐based hydroxyl‐protected polystyrenes with controlled molecular weights and narrow molecular weight distributions. Subsequent deprotection of the silyl groups under mild conditions results in a series of well‐defined functionalized polystyrenes possessing different numbers (mono‐, di‐, tri‐) of hydroxy groups at different positions (o , m , p ). The obtained functionalized polystyrenes show unique thermal properties depending on the substituents, and those with phenol and catechol groups serve as reducing agents for silver ions. | |||||
言語 | en | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | ファイル公開:2021-01-01 | |||||
言語 | ja | |||||
出版者 | ||||||
出版者 | Wiley | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/pola.29453 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 2642-4150 | |||||
書誌情報 |
en : Journal of Polymer Science 巻 58, 号 1, p. 91-100, 発行日 2020-01-01 |
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著者版フラグ | ||||||
値 | author |