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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes

http://hdl.handle.net/2237/00032514
http://hdl.handle.net/2237/00032514
c811a974-343f-4974-af8a-c110c9312bf1
名前 / ファイル ライセンス アクション
JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100.pdf JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100 (2.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-07-15
タイトル
タイトル Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes
言語 en
著者 Takeshima, Hisaaki

× Takeshima, Hisaaki

WEKO 100610

en Takeshima, Hisaaki

Search repository
Satoh, Kotaro

× Satoh, Kotaro

WEKO 100611

en Satoh, Kotaro

Search repository
Kamigaito, Masami

× Kamigaito, Masami

WEKO 100612

en Kamigaito, Masami

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [Takeshima, H., Satoh, K. and Kamigaito, M. (2020), Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes. J. Polym. Sci., 58: 91-100. doi:10.1002/pola.29453], which has been published in final form at [https://doi.org/10.1002/pola.29453]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
キーワード
主題Scheme Other
主題 bio‐based polymer
キーワード
主題Scheme Other
主題 cinnamic acid
キーワード
主題Scheme Other
主題 hydroxystyrene
キーワード
主題Scheme Other
主題 catechol
キーワード
主題Scheme Other
主題 functionalization of polymers
キーワード
主題Scheme Other
主題 gallol
キーワード
主題Scheme Other
主題 guaiacol
キーワード
主題Scheme Other
主題 living polymerization
キーワード
主題Scheme Other
主題 phenol
キーワード
主題Scheme Other
主題 RAFT
キーワード
主題Scheme Other
主題 radical polymerization
キーワード
主題Scheme Other
主題 syringol
抄録
内容記述 A series of bio‐based vinylphenols or hydroxystyrenes is prepared by simple decarboxylation of various naturally occurring cinnamic acids such as o‐, m‐, and p‐coumaric; caffeic; ferulic; and sinapinic acids, which possess hydroxy groups and other substituents at different positions on the aromatic ring. After protection of the phenolic moieties with trialkylsilyl groups, reversible addition–fragmentation chain‐transfer polymerization is accomplished with cumyl dithiobenzoate to afford various bio‐based hydroxyl‐protected polystyrenes with controlled molecular weights and narrow molecular weight distributions. Subsequent deprotection of the silyl groups under mild conditions results in a series of well‐defined functionalized polystyrenes possessing different numbers (mono‐, di‐, tri‐) of hydroxy groups at different positions (o , m , p ). The obtained functionalized polystyrenes show unique thermal properties depending on the substituents, and those with phenol and catechol groups serve as reducing agents for silver ions.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-01-01
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/pola.29453
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 2642-4150
書誌情報 en : Journal of Polymer Science

巻 58, 号 1, p. 91-100, 発行日 2020-01-01
著者版フラグ
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