{"_buckets": {"deposit": "eb521230-6546-4456-8388-e41456a0df55"}, "_deposit": {"id": "30516", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30516"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030516", "sets": ["696"]}, "author_link": ["101584", "101585", "101586", "101587", "101588", "101589", "101590"], "control_number": "30516", "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageEnd": "8913", "bibliographicPageStart": "8908", "bibliographicVolumeNumber": "11", "bibliographic_titles": [{"bibliographic_title": "The Journal of Physical Chemistry Letters", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The high-spin S2 state was investigated with photosystem II (PSII) from spinach, Thermosynechococcus vulcanus, and Cyanidioschyzon merolae. In extrinsic protein-depleted PSII, high-spin electron paramagnetic resonance (EPR) signals were not detected in either species, whereas all species showed g ∼ 5 signals in the presence of a high concentration of Ca^2+ instead of the multiline signal. In the intact and PsbP/Q-depleted PSII from spinach, the g = 4.1 EPR signal was detected. These results show that formation of the high-spin S2 state of the manganese cluster is regulated by the extrinsic proteins through a charge located near the Mn4 atom in the Mn4CaO5 cluster but is independent of the intrinsic proteins. The shift to the g ∼ 5 state is caused by tilting of the z-axis in the Mn4 coordinates through hydrogen bonds or external divalent cations. The structural modification may allow insertion of an oxygen atom during the S2-to-S3 transition.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Published online: 29 September 2020 ファイル公開：2021-09-29", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.jpclett.0c02411", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-UCBYCVYETEJEWMH7QIBW].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "1948-7185", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Taguchi, Shota", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101584", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shen, Liangliang", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101585", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Han, Guangye", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101586", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Umena, Yasufumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101587", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shen, Jian-Ren", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101588", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Noguchi, Takumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101589", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mino, Hiroyuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101590", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-09-29"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "200926_manuscript_JPCL_pr.pdf", "filesize": [{"value": "927.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 927000.0, "url": {"label": "200926_manuscript_JPCL_pr", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/30516/files/200926_manuscript_JPCL_pr.pdf"}, "version_id": "a5dcea81-753e-4787-a53f-2b0cb6046da2"}, {"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-09-29"}], "displaytype": "detail", "download_preview_message": "", "file_order": 1, "filename": "jz0c02411_si_001.pdf", "filesize": [{"value": "1.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1600000.0, "url": {"label": "jz0c02411_si_001", "objectType": "dataset", "url": "https://nagoya.repo.nii.ac.jp/record/30516/files/jz0c02411_si_001.pdf"}, "version_id": "406f11c1-e1d9-4c98-9b5a-f48dd31c8452"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/00032704", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-10-09"}, "publish_date": "2020-10-09", "publish_status": "0", "recid": "30516", "relation": {}, "relation_version_is_last": true, "title": ["Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II"], "weko_shared_id": -1}