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One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species
http://hdl.handle.net/2237/00032721
http://hdl.handle.net/2237/0003272101719722-93b0-40ae-935f-1eb42b6a71fc
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-10-13 | |||||
タイトル | ||||||
タイトル | One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species | |||||
言語 | en | |||||
著者 |
Sugita, Kengo
× Sugita, Kengo× Yamashita, Makoto |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GYPWGX8TPQK8VPMTVQUT].” | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Transfer reactions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Anions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Absorption | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Electron paramagnetic resonance spectroscopy | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Absorption spectroscopy | |||||
抄録 | ||||||
内容記述 | A reaction of dialkylalumanylpotassium with Ti(O^iPr)4 was investigated. The alumanyl anion worked as a reducing reagent to afford the trivalent titanium complex as a contact ion pair with aluminate anion probably via single-electron transfer. The ESR spectrum revealed the delocalization of an unpaired electron over Ti and Al atoms. The DFT calculations provided information about the ratio of unpaired electrons on Ti and Al atoms and the UV–vis absorption spectrum. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2021-06-08 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.organomet.0c00177 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0276-7333 | |||||
書誌情報 |
en : Organometallics 巻 39, 号 11, p. 2125-2129, 発行日 2020-06-08 |
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著者版フラグ | ||||||
値 | author |