{"_buckets": {"deposit": "0453c796-c76e-4ff9-b1f4-e6311a80da07"}, "_deposit": {"id": "30536", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30536"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030536"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-06-08", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "11", "bibliographicPageEnd": "2129", "bibliographicPageStart": "2125", "bibliographicVolumeNumber": "39", "bibliographic_titles": [{"bibliographic_title": "Organometallics"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A reaction of dialkylalumanylpotassium with Ti(O^iPr)4 was investigated. The alumanyl anion worked as a reducing reagent to afford the trivalent titanium complex as a contact ion pair with aluminate anion probably via single-electron transfer. The ESR spectrum revealed the delocalization of an unpaired electron over Ti and Al atoms. The DFT calculations provided information about the ratio of unpaired electrons on Ti and Al atoms and the UV\u2013vis absorption spectrum.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-06-08", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.organomet.0c00177", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GYPWGX8TPQK8VPMTVQUT].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0276-7333", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sugita, Kengo"}], "nameIdentifiers": [{"nameIdentifier": "101631", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "101632", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-06-08"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Text_20200501.pdf", "filesize": [{"value": "982.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 982800.0, "url": {"label": "Text_20200501", "url": "https://nagoya.repo.nii.ac.jp/record/30536/files/Text_20200501.pdf"}, "version_id": "c1b57e86-69d7-49ab-a3b1-13d331bd263d"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Transfer reactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Anions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Absorption", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electron paramagnetic resonance spectroscopy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Absorption spectroscopy", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032721", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-10-13"}, "publish_date": "2020-10-13", "publish_status": "0", "recid": "30536", "relation": {}, "relation_version_is_last": true, "title": ["One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species"], "weko_shared_id": null}