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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species

http://hdl.handle.net/2237/00032721
http://hdl.handle.net/2237/00032721
01719722-93b0-40ae-935f-1eb42b6a71fc
名前 / ファイル ライセンス アクション
Text_20200501.pdf Text_20200501 (982.8 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-10-13
タイトル
タイトル One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species
言語 en
著者 Sugita, Kengo

× Sugita, Kengo

WEKO 101631

en Sugita, Kengo

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 101632

en Yamashita, Makoto

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GYPWGX8TPQK8VPMTVQUT].”
キーワード
主題Scheme Other
主題 Transfer reactions
キーワード
主題Scheme Other
主題 Anions
キーワード
主題Scheme Other
主題 Absorption
キーワード
主題Scheme Other
主題 Electron paramagnetic resonance spectroscopy
キーワード
主題Scheme Other
主題 Absorption spectroscopy
抄録
内容記述 A reaction of dialkylalumanylpotassium with Ti(O^iPr)4 was investigated. The alumanyl anion worked as a reducing reagent to afford the trivalent titanium complex as a contact ion pair with aluminate anion probably via single-electron transfer. The ESR spectrum revealed the delocalization of an unpaired electron over Ti and Al atoms. The DFT calculations provided information about the ratio of unpaired electrons on Ti and Al atoms and the UV–vis absorption spectrum.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-06-08
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.organomet.0c00177
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0276-7333
書誌情報 en : Organometallics

巻 39, 号 11, p. 2125-2129, 発行日 2020-06-08
著者版フラグ
値 author
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