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A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands
http://hdl.handle.net/2237/00033198
http://hdl.handle.net/2237/000331986e939764-4d7b-4be5-95fe-eb2334232152
名前 / ファイル | ライセンス | アクション |
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ChemComm_manuscript-rev2 (730.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-12-15 | |||||
タイトル | ||||||
タイトル | A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands | |||||
言語 | en | |||||
著者 |
Ohki, Yasuhiro
× Ohki, Yasuhiro× Ishihara, Kodai× Yaoi, Moeko× Tada, Mizuki× Sameera, W. M. C.× Cramer, Roger E. |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
抄録 | ||||||
内容記述 | Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp‡) ligands, Cp‡2Mo2H8 (1), from the reaction of Cp‡MoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 °C to afford a μ-benzene complex Cp‡2Mo2H2(μ-C6H6) (2). | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2021/07/25 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Royal Society of Chemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/D0CC03274C | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1359-7345 | |||||
書誌情報 |
en : Chemical Communications 巻 56, 号 58, p. 8035-8038, 発行日 2020-07-25 |
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著者版フラグ | ||||||
値 | publisher |