{"_buckets": {"deposit": "8c4219c4-a6c3-45a5-aa9c-8bc533c06ad5"}, "_deposit": {"id": "31015", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "31015"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00031015"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-07-25", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "58", "bibliographicPageEnd": "8038", "bibliographicPageStart": "8035", "bibliographicVolumeNumber": "56", "bibliographic_titles": [{"bibliographic_title": "Chemical Communications"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp\u2021) ligands, Cp\u20212Mo2H8 (1), from the reaction of Cp\u2021MoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 \u00b0C to afford a \u03bc-benzene complex Cp\u20212Mo2H2(\u03bc-C6H6) (2).", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021/07/25", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/D0CC03274C", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1359-7345", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohki, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "102554", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishihara, Kodai"}], "nameIdentifiers": [{"nameIdentifier": "102555", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yaoi, Moeko"}], "nameIdentifiers": [{"nameIdentifier": "102556", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Mizuki"}], "nameIdentifiers": [{"nameIdentifier": "102557", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sameera, W. M. C."}], "nameIdentifiers": [{"nameIdentifier": "102558", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Cramer, Roger E."}], "nameIdentifiers": [{"nameIdentifier": "102559", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-07-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ChemComm_manuscript-rev2.pdf", "filesize": [{"value": "730.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 730000.0, "url": {"label": "ChemComm_manuscript-rev2", "url": "https://nagoya.repo.nii.ac.jp/record/31015/files/ChemComm_manuscript-rev2.pdf"}, "version_id": "12db77eb-bbea-4d4e-86c3-f934051d422f"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/00033198", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-12-15"}, "publish_date": "2020-12-15", "publish_status": "0", "recid": "31015", "relation": {}, "relation_version_is_last": true, "title": ["A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands"], "weko_shared_id": null}