WEKO3
アイテム
{"_buckets": {"deposit": "1145c242-f29a-4212-87f7-9d3307e29a16"}, "_deposit": {"id": "9522", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "9522"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00009522", "sets": ["696"]}, "author_link": ["27303", "27304", "27305", "27306", "27307"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "17", "bibliographicPageEnd": "172409", "bibliographicPageStart": "172409", "bibliographicVolumeNumber": "76", "bibliographic_titles": [{"bibliographic_title": "PHYSICAL REVIEW B", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Synchrotron soft x-ray magnetic circular dichroism (SXMCD) spectroscopy at the Gd and Dy M_5 edges is reported on endohedral metallofullerenes (M@C_82, M=Gd and Dy) and the corresponding nanopeapods [M@C_82)@SWNT, SWNT represents single wall carbon nanotube] in a temperature range between 10 and 40 K. The magnetic moment has also been determined by theoretical calculations, which are based on the Hartree-Fock approximation with relativistic corrections. Because of the element-specific measurement of SXMCD, magnetization processes of Gd and Dy ions of nanopeapods have been selectively observed. The temperature dependence of magnetic moments of the metallofullerenes and nanopeapods follows the Curie- Weiss law with a small Weiss temperature, indicating that the magnetic interaction between encapsulated rare-earth metal atoms is relatively weak. Although the observed differences in Curie constants and Weiss temperatures between Gd@C_82 and (Gd@C_82)@SWNT are small, those of Dy@C_82 and (Dy@C_82)@SWNT are significant. This observation is consistently explained by charge transfer-induced crystal-field effects.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/11305"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Physical Society", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1103/PhysRevB.76.172409", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "American Physical Society, All rights reserved.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1098-0121", "subitem_source_identifier_type": "PISSN"}]}, "item_10_text_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kitaura, R.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "27303", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okimoto, H.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "27304", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinohara, H.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "27305", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakamura, T.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "27306", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Osawa, H.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "27307", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PhysRevB_76_172409.pdf", "filesize": [{"value": "327.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 327200.0, "url": {"label": "PhysRevB_76_172409.pdf", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/9522/files/PhysRevB_76_172409.pdf"}, "version_id": "0c23e6dc-4291-4655-b2d9-35b8cc5417c9"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "carbon nanotubes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "charge exchange", "subitem_subject_scheme": "Other"}, {"subitem_subject": "crystal field interactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "density functional theory", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dysprosium", "subitem_subject_scheme": "Other"}, {"subitem_subject": "exchange interactions (electron)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "fullerenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "gadolinium", "subitem_subject_scheme": "Other"}, {"subitem_subject": "HF calculations", "subitem_subject_scheme": "Other"}, {"subitem_subject": "magnetic circular dichroism", "subitem_subject_scheme": "Other"}, {"subitem_subject": "magnetic moments", "subitem_subject_scheme": "Other"}, {"subitem_subject": "magnetic susceptibility", "subitem_subject_scheme": "Other"}, {"subitem_subject": "magnetisation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "X-ray diffraction", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Magnetism of the endohedral metallofullerenes M@C_82 (M=Gd,Dy) and the corresponding nanoscale peapods: Synchrotron soft x-ray magnetic circular dichroism and density-functional theory calculations", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Magnetism of the endohedral metallofullerenes M@C_82 (M=Gd,Dy) and the corresponding nanoscale peapods: Synchrotron soft x-ray magnetic circular dichroism and density-functional theory calculations", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/11305", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2009-03-12"}, "publish_date": "2009-03-12", "publish_status": "0", "recid": "9522", "relation": {}, "relation_version_is_last": true, "title": ["Magnetism of the endohedral metallofullerenes M@C_82 (M=Gd,Dy) and the corresponding nanoscale peapods: Synchrotron soft x-ray magnetic circular dichroism and density-functional theory calculations"], "weko_shared_id": -1}
Magnetism of the endohedral metallofullerenes M@C_82 (M=Gd,Dy) and the corresponding nanoscale peapods: Synchrotron soft x-ray magnetic circular dichroism and density-functional theory calculations
http://hdl.handle.net/2237/11305
http://hdl.handle.net/2237/113053e9ede0d-ab12-4ef6-a5b0-f54e2307781e
名前 / ファイル | ライセンス | アクション |
---|---|---|
PhysRevB_76_172409.pdf (327.2 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2009-03-12 | |||||
タイトル | ||||||
タイトル | Magnetism of the endohedral metallofullerenes M@C_82 (M=Gd,Dy) and the corresponding nanoscale peapods: Synchrotron soft x-ray magnetic circular dichroism and density-functional theory calculations | |||||
言語 | en | |||||
著者 |
Kitaura, R.
× Kitaura, R.× Okimoto, H.× Shinohara, H.× Nakamura, T.× Osawa, H. |
|||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | American Physical Society, All rights reserved. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | carbon nanotubes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | charge exchange | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | crystal field interactions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | density functional theory | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | dysprosium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | exchange interactions (electron) | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | fullerenes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | gadolinium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | HF calculations | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | magnetic circular dichroism | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | magnetic moments | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | magnetic susceptibility | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | magnetisation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | X-ray diffraction | |||||
抄録 | ||||||
内容記述 | Synchrotron soft x-ray magnetic circular dichroism (SXMCD) spectroscopy at the Gd and Dy M_5 edges is reported on endohedral metallofullerenes (M@C_82, M=Gd and Dy) and the corresponding nanopeapods [M@C_82)@SWNT, SWNT represents single wall carbon nanotube] in a temperature range between 10 and 40 K. The magnetic moment has also been determined by theoretical calculations, which are based on the Hartree-Fock approximation with relativistic corrections. Because of the element-specific measurement of SXMCD, magnetization processes of Gd and Dy ions of nanopeapods have been selectively observed. The temperature dependence of magnetic moments of the metallofullerenes and nanopeapods follows the Curie- Weiss law with a small Weiss temperature, indicating that the magnetic interaction between encapsulated rare-earth metal atoms is relatively weak. Although the observed differences in Curie constants and Weiss temperatures between Gd@C_82 and (Gd@C_82)@SWNT are small, those of Dy@C_82 and (Dy@C_82)@SWNT are significant. This observation is consistently explained by charge transfer-induced crystal-field effects. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | American Physical Society | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1103/PhysRevB.76.172409 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1098-0121 | |||||
書誌情報 |
en : PHYSICAL REVIEW B 巻 76, 号 17, p. 172409-172409, 発行日 2007-11 |
|||||
フォーマット | ||||||
application/pdf | ||||||
著者版フラグ | ||||||
値 | publisher | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/11305 | |||||
識別子タイプ | HDL |