ログイン
言語:

WEKO3

  • トップ
  • コミュニティ
  • ランキング
AND
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "561c4c51-5da4-46c8-b1b0-beec8a4d4e4c"}, "_deposit": {"id": "22899", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "22899"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00022899"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-06-06", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "24", "bibliographicPageEnd": "6876", "bibliographicPageStart": "6873", "bibliographicVolumeNumber": "55", "bibliographic_titles": [{"bibliographic_title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently \u03b3,\u03b3-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the \u03b3\u2005position is described. Chiral rhodium\u2013bis(oxazolinyl)phenyl complexes 1 were effective catalysts for this transformation. This catalytic system was extended to the asymmetric transformation of spirocarbocyclic cyclohexadienones 5 to give the corresponding products 6 with high enantiomeric ratios.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/anie.201601636"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25079"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.24, 2016, p.6873\u20136876], which has been published in final form at [http://doi.org/10.1002/anie.201601636]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Naganawa, Yuki"}], "nameIdentifiers": [{"nameIdentifier": "67384", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawagishi, Mayu"}], "nameIdentifiers": [{"nameIdentifier": "67385", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito, Jun-ichi"}], "nameIdentifiers": [{"nameIdentifier": "67386", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiyama, Hisao"}], "nameIdentifiers": [{"nameIdentifier": "67387", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-06-06"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "6322ACIE.PDF", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "6322ACIE.PDF \u30d5\u30a1\u30a4\u30eb\u516c\u958b:2017-06-06", "url": "https://nagoya.repo.nii.ac.jp/record/22899/files/6322ACIE.PDF"}, "version_id": "68d45dae-f359-4c1a-b8cc-d88c374ea239"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/25079", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2016-11-22"}, "publish_date": "2016-11-22", "publish_status": "0", "recid": "22899", "relation": {}, "relation_version_is_last": true, "title": ["Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation"], "weko_shared_id": null}
  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation

http://hdl.handle.net/2237/25079
97bcb323-ef2f-4431-9945-6d56834967b9
名前 / ファイル ライセンス アクション
6322ACIE.PDF 6322ACIE.PDF ファイル公開:2017-06-06 (1.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-11-22
タイトル
タイトル Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation
著者 Naganawa, Yuki

× Naganawa, Yuki

WEKO 67384

Naganawa, Yuki

Search repository
Kawagishi, Mayu

× Kawagishi, Mayu

WEKO 67385

Kawagishi, Mayu

Search repository
Ito, Jun-ichi

× Ito, Jun-ichi

WEKO 67386

Ito, Jun-ichi

Search repository
Nishiyama, Hisao

× Nishiyama, Hisao

WEKO 67387

Nishiyama, Hisao

Search repository
権利
権利情報 "This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.24, 2016, p.6873–6876], which has been published in final form at [http://doi.org/10.1002/anie.201601636]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
抄録
内容記述 The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently γ,γ-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the γ position is described. Chiral rhodium–bis(oxazolinyl)phenyl complexes 1 were effective catalysts for this transformation. This catalytic system was extended to the asymmetric transformation of spirocarbocyclic cyclohexadienones 5 to give the corresponding products 6 with high enantiomeric ratios.
内容記述タイプ Abstract
出版者
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1433-7851
書誌情報 ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

巻 55, 号 24, p. 6873-6876, 発行日 2016-06-06
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/anie.201601636
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25079
識別子タイプ HDL
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 14:47:28.910074
Show All versions

Share

Mendeley CiteULike Twitter Facebook Print Addthis

Cite as

Export

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by CERN Data Centre & Invenio


Powered by CERN Data Centre & Invenio