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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation

http://hdl.handle.net/2237/25079
http://hdl.handle.net/2237/25079
97bcb323-ef2f-4431-9945-6d56834967b9
名前 / ファイル ライセンス アクション
6322ACIE.PDF 6322ACIE.PDF ファイル公開:2017-06-06 (1.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-11-22
タイトル
タイトル Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation
言語 en
著者 Naganawa, Yuki

× Naganawa, Yuki

WEKO 67384

en Naganawa, Yuki

Search repository
Kawagishi, Mayu

× Kawagishi, Mayu

WEKO 67385

en Kawagishi, Mayu

Search repository
Ito, Jun-ichi

× Ito, Jun-ichi

WEKO 67386

en Ito, Jun-ichi

Search repository
Nishiyama, Hisao

× Nishiyama, Hisao

WEKO 67387

en Nishiyama, Hisao

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.24, 2016, p.6873–6876], which has been published in final form at [http://doi.org/10.1002/anie.201601636]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently γ,γ-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the γ position is described. Chiral rhodium–bis(oxazolinyl)phenyl complexes 1 were effective catalysts for this transformation. This catalytic system was extended to the asymmetric transformation of spirocarbocyclic cyclohexadienones 5 to give the corresponding products 6 with high enantiomeric ratios.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201601636
ISSN
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

巻 55, 号 24, p. 6873-6876, 発行日 2016-06-06
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/anie.201601636
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25079
識別子タイプ HDL
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