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Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides
http://hdl.handle.net/2237/25698
http://hdl.handle.net/2237/256981875bf38-35ef-4e44-a718-f8ef12ae9a2f
名前 / ファイル | ライセンス | アクション |
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manuscript-rev-final.pdf ファイル公開:2017/12/19 (1.2 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-03-14 | |||||
タイトル | ||||||
タイトル | Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides | |||||
言語 | en | |||||
著者 |
Ohki, Yasuhiro
× Ohki, Yasuhiro× Shimizu, Yuki× Araake, Ryoichi× Tada, Mizuki× Sameera, W.M.C× Ito, Jun-Ichi× Nishiyama, Hisao |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [Y. Ohki, Y. Shimizu, R. Araake, M. Tada, W. M. C. Sameera, J.-I. Ito, H. Nishiyama, Angew. Chem. Int. Ed. 2016, 55, 15821.], which has been published in final form at [http://doi.org/10.1002/anie.201608262]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A square-planar Co4 amide cluster, Co4{N(SiMe3)2}4 (2), and an octahedral Co6 hydride cluster, Co6H8(PiPr3)6 (4), were obtained from metathesis-type amide to hydride exchange reactions of a CoII amide complex with pinacolborane (HBpin) in the absence/presence of PiPr3. The crystal structure of 4 revealed face-capping hydrides on each triangular [Co3] face, while the formal CoII2CoI4 oxidation state of 4 indicated a reduction of the cobalt centers during the assembly process. Cluster 4 catalyzes the hydrosilylation of 2-cyclohexen-1-one favoring the conjugate reduction. Generation of the catalytically reactive Co cluster species was indicated by a trapping experiment with a chiral chelating agent. | |||||
言語 | en | |||||
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出版者 | Wiley | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/anie.201608262 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1433-7851 | |||||
書誌情報 |
en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 巻 55, 号 51, p. 15821-15825, 発行日 2016-12-19 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1002/anie.201608262 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25698 | |||||
識別子タイプ | HDL |