{"_buckets": {"deposit": "5106cd4e-74a5-493b-b605-f24b09adfa3f"}, "_deposit": {"id": "24762", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24762"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024762", "sets": ["322"]}, "author_link": ["73598", "73599", "73600"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-06-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "33", "bibliographicPageEnd": "7870", "bibliographicPageStart": "7866", "bibliographicVolumeNumber": "22", "bibliographic_titles": [{"bibliographic_title": "CHEMISTRY-A EUROPEAN JOURNAL", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(α,α′-dibromodipyrrin) Ni^II precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and Zn^II 10-silacorroles exhibit emissions in the NIR region. Theoretical calculations on these 10-silacorroles revealed the presence of σ*–π* conjugation between the silyl group and the tetrapyrrole π system, which significantly lowers their LUMO energy levels.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/chem.201701474"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26985"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201701474", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [H.Omori,S.Hiroto, H.Shinokubo,Chem. Eur. J. 2017, 23, 7866.], which has been published in final form at [http://doi.org/10.1002/chem.201701474]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Omori, Hiroto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73598", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroto, Satoru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73599", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73600", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "CEJ_170424HO_rev.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "CEJ_170424HO_rev.pdf ファイル公開:2018/06/12", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/24762/files/CEJ_170424HO_rev.pdf"}, "version_id": "7a25677c-d1b1-4dbc-a7f4-752c359d307b"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "10-heterocorroles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dyes/pigments", "subitem_subject_scheme": "Other"}, {"subitem_subject": "silicon", "subitem_subject_scheme": "Other"}, {"subitem_subject": "porphyrinoids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "NIR emission", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "10-Silacorroles Exhibiting NIR Absorption and Emission", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "10-Silacorroles Exhibiting NIR Absorption and Emission", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/26985", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-10-04"}, "publish_date": "2017-10-04", "publish_status": "0", "recid": "24762", "relation": {}, "relation_version_is_last": true, "title": ["10-Silacorroles Exhibiting NIR Absorption and Emission"], "weko_shared_id": -1}