{"_buckets": {"deposit": "5106cd4e-74a5-493b-b605-f24b09adfa3f"}, "_deposit": {"id": "24762", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24762"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024762"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-06-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "33", "bibliographicPageEnd": "7870", "bibliographicPageStart": "7866", "bibliographicVolumeNumber": "22", "bibliographic_titles": [{"bibliographic_title": "CHEMISTRY-A EUROPEAN JOURNAL"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(\u03b1,\u03b1\u2032-dibromodipyrrin) Ni^II precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and Zn^II\u200510-silacorroles exhibit emissions in the NIR region. Theoretical calculations on these 10-silacorroles revealed the presence of \u03c3*\u2013\u03c0* conjugation between the silyl group and the tetrapyrrole \u03c0\u2005system, which significantly lowers their LUMO energy levels.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/chem.201701474"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26985"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [H.Omori,S.Hiroto, H.Shinokubo,Chem. Eur. J. 2017, 23, 7866.], which has been published in final form at [http://doi.org/10.1002/chem.201701474]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Omori, Hiroto"}], "nameIdentifiers": [{"nameIdentifier": "73598", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroto, Satoru"}], "nameIdentifiers": [{"nameIdentifier": "73599", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "73600", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "CEJ_170424HO_rev.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "CEJ_170424HO_rev.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b:2018/06/12", "url": "https://nagoya.repo.nii.ac.jp/record/24762/files/CEJ_170424HO_rev.pdf"}, "version_id": "7a25677c-d1b1-4dbc-a7f4-752c359d307b"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "10-heterocorroles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dyes/pigments", "subitem_subject_scheme": "Other"}, {"subitem_subject": "silicon", "subitem_subject_scheme": "Other"}, {"subitem_subject": "porphyrinoids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "NIR emission", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "10-Silacorroles Exhibiting NIR Absorption and Emission", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "10-Silacorroles Exhibiting NIR Absorption and Emission"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/26985", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-10-04"}, "publish_date": "2017-10-04", "publish_status": "0", "recid": "24762", "relation": {}, "relation_version_is_last": true, "title": ["10-Silacorroles Exhibiting NIR Absorption and Emission"], "weko_shared_id": null}