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Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols
http://hdl.handle.net/2237/00029364
http://hdl.handle.net/2237/000293643fe89952-b513-41e3-b480-cc36bb27c42f
名前 / ファイル | ライセンス | アクション |
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Revision (7.4 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-03-05 | |||||
タイトル | ||||||
タイトル | Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols | |||||
言語 | en | |||||
著者 |
Okamoto, Haruka
× Okamoto, Haruka× Toh, Kohei× Mochizuki, Takuya× Nakatsuji, Hidefumi× Sakakura, Akira× Hatano, Manabu× Ishihara, Kazuaki |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Brønsted acid | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | phosphoric acid | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | pyrophosphoric acid | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | organocatalyst | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | aza-Friedel–Crafts reaction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | phenol | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | regio-selectivity | |||||
抄録 | ||||||
内容記述 | Chiral BINOL-derived pyrophosphoric acid catalysts were developed and used for the regio- and enantioselective aza-Friedel–Crafts reaction of phenols with aldimines. ortho/para-Directing phenols could react at the para-position selectively with moderate to good enantioselectivities. Moreover, the gram-scale transformation of a product into the key intermediate for the antifungal agent (R)-bifonazole was demonstrated. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019/12/01 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Georg Thieme Verlag | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1055/s-0037-1610250 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0039-7881 | |||||
書誌情報 |
en : Synthesis 巻 50, 号 23, p. 4577-4590, 発行日 2018-12 |
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著者版フラグ | ||||||
値 | author |