{"_buckets": {"deposit": "ffe717ca-c5e4-4c94-8802-ebd8e0d096e6"}, "_deposit": {"id": "27179", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27179"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027179"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-11-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "11", "bibliographicPageEnd": "15424", "bibliographicPageStart": "15419", "bibliographicVolumeNumber": "6", "bibliographic_titles": [{"bibliographic_title": "ACS Sustainable Chemistry \u0026 Engineering"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Amines in heteroaromatic systems and pharmaceutical intermediates were functionalized through N-methylation with methanol using a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. This method provides access to a series of tertiary N-methylamines bearing N-, O-, and/or S-containing heteroaromatic functionalities from primary/secondary amines and methanol under mild reaction conditions. Facile syntheses of several pharmaceuticals containing N-methyl or ethyl groups, as well as related deuterated drugs, was achieved through the late-stage functionalization of amines.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-11-05", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acssuschemeng.8b03855", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Sustainable Chemistry \u0026 Engineering], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-G2mCKTXg7y5BCEnWAmU9].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "2168-0485", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Wang, Lyu-Ming"}], "nameIdentifiers": [{"nameIdentifier": "89074", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Jenkinson, Kellie"}], "nameIdentifiers": [{"nameIdentifier": "89075", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wheatley, Andrew E. H."}], "nameIdentifiers": [{"nameIdentifier": "89076", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuwata, Keiko"}], "nameIdentifiers": [{"nameIdentifier": "89077", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saito, Susumu"}], "nameIdentifiers": [{"nameIdentifier": "89078", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Naka, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "89079", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-11-05"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Pd_8926.pdf", "filesize": [{"value": "714.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 714900.0, "url": {"label": "Pd_8926", "url": "https://nagoya.repo.nii.ac.jp/record/27179/files/Pd_8926.pdf"}, "version_id": "a4134096-0e31-417b-bd11-652f59e0a6a8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Green chemistry", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Methanol", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Methylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pharmaceuticals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Photocatalysis", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates"}]}, "item_type_id": "10", "owner": "1", "path": ["1917/1918/1919"], "permalink_uri": "http://hdl.handle.net/2237/00029385", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2019-03-06"}, "publish_date": "2019-03-06", "publish_status": "0", "recid": "27179", "relation": {}, "relation_version_is_last": true, "title": ["Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates"], "weko_shared_id": null}