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Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates
http://hdl.handle.net/2237/00029385
http://hdl.handle.net/2237/00029385c0ca35e6-e4ac-46d3-a042-9db24250778e
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Pd_8926 (714.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-03-06 | |||||
| タイトル | ||||||
| タイトル | Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates | |||||
| 言語 | en | |||||
| 著者 |
Wang, Lyu-Ming
× Wang, Lyu-Ming× Jenkinson, Kellie× Wheatley, Andrew E. H.× Kuwata, Keiko× Saito, Susumu× Naka, Hiroshi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Sustainable Chemistry & Engineering], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-G2mCKTXg7y5BCEnWAmU9].” | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Green chemistry | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Methanol | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Methylation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Pharmaceuticals | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Photocatalysis | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Amines in heteroaromatic systems and pharmaceutical intermediates were functionalized through N-methylation with methanol using a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. This method provides access to a series of tertiary N-methylamines bearing N-, O-, and/or S-containing heteroaromatic functionalities from primary/secondary amines and methanol under mild reaction conditions. Facile syntheses of several pharmaceuticals containing N-methyl or ethyl groups, as well as related deuterated drugs, was achieved through the late-stage functionalization of amines. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2019-11-05 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/acssuschemeng.8b03855 | |||||
| ISSN（Online） | ||||||
| 収録物識別子タイプ | EISSN | |||||
| 収録物識別子 | 2168-0485 | |||||
| 書誌情報 |
en : ACS Sustainable Chemistry & Engineering 巻 6, 号 11, p. 15419-15424, 発行日 2018-11-05 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
