{"_buckets": {"deposit": "0158a58e-a100-444b-899f-5a316665268f"}, "_deposit": {"id": "27209", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27209"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027209"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-11-16", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "64", "bibliographicPageEnd": "17147", "bibliographicPageStart": "17138", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "Chemistry \u2013 A European Journal"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A synthetic protocol was developed for a series of cubane\u2010type [Mo3S4M] clusters that incorporate halides of first\u2010row transition metals (M) from Groups\u20054\u201310. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^\u2212 ([1]^\u2212; Cp^*=\u03b7^5\u2010C5Me5), which crystallizes when K(18\u2010crown\u20106) is used as the counter cation. Treatment of in situ\u2010generated [1]^\u2212 with such transition\u2010metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster\u20056\u2009a were investigated in detail by using 57Fe M\u00f6ssbauer spectroscopy and computational methods.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-11-16", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201804083", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sameera, Chem. Eur. J. 2018, 24, 17138.], which has been published in final form at [https://doi.org/10.1002/chem.201804083]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1521-3765", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohki, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "89138", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uchida, Keisuke"}], "nameIdentifiers": [{"nameIdentifier": "89139", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hara, Ryota"}], "nameIdentifiers": [{"nameIdentifier": "89140", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kachi, Mami"}], "nameIdentifiers": [{"nameIdentifier": "89141", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujisawa, Mayu"}], "nameIdentifiers": [{"nameIdentifier": "89142", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Mizuki"}], "nameIdentifiers": [{"nameIdentifier": "89143", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai, Yoichi"}], "nameIdentifiers": [{"nameIdentifier": "89144", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sameera, W. M. C."}], "nameIdentifiers": [{"nameIdentifier": "89145", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-11-16"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "accepted_Mo3S4M_manuscript_CEJ.pdf", "filesize": [{"value": "1.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1800000.0, "url": {"label": "accepted_Mo3S4M_manuscript_CEJ", "url": "https://nagoya.repo.nii.ac.jp/record/27209/files/accepted_Mo3S4M_manuscript_CEJ.pdf"}, "version_id": "e70f85e7-02f2-4398-9039-973a80ec6830"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "clusters", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cubane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "first-row transition metals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "molybdenum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "sulfur", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cubane\u2010Type [Mo3S4M] Clusters with First\u2010Row Groups\u20054\u201310 Transition\u2010Metal Halides Supported by C5Me5 Ligands on Molybdenum", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Cubane\u2010Type [Mo3S4M] Clusters with First\u2010Row Groups\u20054\u201310 Transition\u2010Metal Halides Supported by C5Me5 Ligands on Molybdenum"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/00029408", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2019-03-07"}, "publish_date": "2019-03-07", "publish_status": "0", "recid": "27209", "relation": {}, "relation_version_is_last": true, "title": ["Cubane\u2010Type [Mo3S4M] Clusters with First\u2010Row Groups\u20054\u201310 Transition\u2010Metal Halides Supported by C5Me5 Ligands on Molybdenum"], "weko_shared_id": null}