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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum

http://hdl.handle.net/2237/00029408
http://hdl.handle.net/2237/00029408
9b8a0acb-7f49-478e-a458-9bf195842935
名前 / ファイル ライセンス アクション
accepted_Mo3S4M_manuscript_CEJ.pdf accepted_Mo3S4M_manuscript_CEJ (1.8 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-03-07
タイトル
タイトル Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum
言語 en
著者 Ohki, Yasuhiro

× Ohki, Yasuhiro

WEKO 89138

en Ohki, Yasuhiro

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Uchida, Keisuke

× Uchida, Keisuke

WEKO 89139

en Uchida, Keisuke

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Hara, Ryota

× Hara, Ryota

WEKO 89140

en Hara, Ryota

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Kachi, Mami

× Kachi, Mami

WEKO 89141

en Kachi, Mami

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Fujisawa, Mayu

× Fujisawa, Mayu

WEKO 89142

en Fujisawa, Mayu

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Tada, Mizuki

× Tada, Mizuki

WEKO 89143

en Tada, Mizuki

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Sakai, Yoichi

× Sakai, Yoichi

WEKO 89144

en Sakai, Yoichi

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Sameera, W. M. C.

× Sameera, W. M. C.

WEKO 89145

en Sameera, W. M. C.

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sameera, Chem. Eur. J. 2018, 24, 17138.], which has been published in final form at [https://doi.org/10.1002/chem.201804083]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
キーワード
主題Scheme Other
主題 clusters
キーワード
主題Scheme Other
主題 cubane
キーワード
主題Scheme Other
主題 first-row transition metals
キーワード
主題Scheme Other
主題 molybdenum
キーワード
主題Scheme Other
主題 sulfur
抄録
内容記述 A synthetic protocol was developed for a series of cubane‐type [Mo3S4M] clusters that incorporate halides of first‐row transition metals (M) from Groups 4–10. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^− ([1]^−; Cp^*=η^5‐C5Me5), which crystallizes when K(18‐crown‐6) is used as the counter cation. Treatment of in situ‐generated [1]^− with such transition‐metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster 6 a were investigated in detail by using 57Fe Mössbauer spectroscopy and computational methods.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2019-11-16
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201804083
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0947-6539
ISSN(Online)
収録物識別子タイプ EISSN
収録物識別子 1521-3765
書誌情報 en : Chemistry – A European Journal

巻 24, 号 64, p. 17138-17147, 発行日 2018-11-16
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