{"_buckets": {"deposit": "0158a58e-a100-444b-899f-5a316665268f"}, "_deposit": {"id": "27209", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27209"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027209", "sets": ["696"]}, "author_link": ["89138", "89139", "89140", "89141", "89142", "89143", "89144", "89145"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-11-16", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "64", "bibliographicPageEnd": "17147", "bibliographicPageStart": "17138", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "Chemistry – A European Journal", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A synthetic protocol was developed for a series of cubane‐type [Mo3S4M] clusters that incorporate halides of first‐row transition metals (M) from Groups 4–10. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^− ([1]^−; Cp^*=η^5‐C5Me5), which crystallizes when K(18‐crown‐6) is used as the counter cation. Treatment of in situ‐generated [1]^− with such transition‐metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster 6 a were investigated in detail by using 57Fe Mössbauer spectroscopy and computational methods.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2019-11-16", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201804083", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sameera, Chem. Eur. J. 2018, 24, 17138.], which has been published in final form at [https://doi.org/10.1002/chem.201804083]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "PISSN"}]}, "item_10_source_id_62": {"attribute_name": "ISSN（Online）", "attribute_value_mlt": [{"subitem_source_identifier": "1521-3765", "subitem_source_identifier_type": "EISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohki, Yasuhiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89138", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uchida, Keisuke", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89139", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hara, Ryota", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89140", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kachi, Mami", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89141", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujisawa, Mayu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89142", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Mizuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89143", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai, Yoichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89144", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sameera, W. M. C.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "89145", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-11-16"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "accepted_Mo3S4M_manuscript_CEJ.pdf", "filesize": [{"value": "1.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1800000.0, "url": {"label": "accepted_Mo3S4M_manuscript_CEJ", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/27209/files/accepted_Mo3S4M_manuscript_CEJ.pdf"}, "version_id": "e70f85e7-02f2-4398-9039-973a80ec6830"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "clusters", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cubane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "first-row transition metals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "molybdenum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "sulfur", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/00029408", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-03-07"}, "publish_date": "2019-03-07", "publish_status": "0", "recid": "27209", "relation": {}, "relation_version_is_last": true, "title": ["Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum"], "weko_shared_id": -1}