WEKO3
アイテム
Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum
http://hdl.handle.net/2237/00029408
http://hdl.handle.net/2237/000294089b8a0acb-7f49-478e-a458-9bf195842935
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
accepted_Mo3S4M_manuscript_CEJ (1.8 MB)
|
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-03-07 | |||||
| タイトル | ||||||
| タイトル | Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum | |||||
| 言語 | en | |||||
| 著者 |
Ohki, Yasuhiro
× Ohki, Yasuhiro× Uchida, Keisuke× Hara, Ryota× Kachi, Mami× Fujisawa, Mayu× Tada, Mizuki× Sakai, Yoichi× Sameera, W. M. C. |
|||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | This is the peer reviewed version of the following article: [Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sameera, Chem. Eur. J. 2018, 24, 17138.], which has been published in final form at [https://doi.org/10.1002/chem.201804083]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | clusters | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cubane | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | first-row transition metals | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | molybdenum | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | sulfur | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A synthetic protocol was developed for a series of cubane‐type [Mo3S4M] clusters that incorporate halides of first‐row transition metals (M) from Groups 4–10. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^− ([1]^−; Cp^*=η^5‐C5Me5), which crystallizes when K(18‐crown‐6) is used as the counter cation. Treatment of in situ‐generated [1]^− with such transition‐metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster 6 a were investigated in detail by using 57Fe Mössbauer spectroscopy and computational methods. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2019-11-16 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/chem.201804083 | |||||
| ISSN（print） | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0947-6539 | |||||
| ISSN（Online） | ||||||
| 収録物識別子タイプ | EISSN | |||||
| 収録物識別子 | 1521-3765 | |||||
| 書誌情報 |
en : Chemistry – A European Journal 巻 24, 号 64, p. 17138-17147, 発行日 2018-11-16 |
|||||
| 著者版フラグ | ||||||
| 値 | author | |||||
