{"_buckets": {"deposit": "c84f5d9e-2687-4c66-ad5e-aee8fa12fcf1"}, "_deposit": {"id": "27947", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27947"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027947", "sets": ["1919"]}, "author_link": ["90988", "90989", "90990"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-01-16", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "830", "bibliographicPageStart": "825", "bibliographicVolumeNumber": "141", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We report the palladium(II)-catalyzed transfer hydration of cyanohydrins to α-hydroxyamides by using carboxamides as water donors. This method enables selective hydration of various aldehyde- and ketone-derived cyanohydrins to afford α-mono- and α,α-disubstituted-α-hydroxyamides, respectively, under mild conditions (50 °C, 10 min). The direct conversion of fenofibrate, a drug bearing a benzophenone moiety, into a functionalized α,α-diaryl-α-hydroxyamide was achieved by means of a hydrocyanation–transfer hydration sequence. Preliminary kinetic studies and the synthesis of a site-specifically 18O-labeled α-hydroxyamide demonstrated the carbonyl oxygen transfer from the carboxamide reagent into the α-hydroxyamide product.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2020-01-16", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.8b12877", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-G2mCKTXg7y5BCEnWAmU9].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kanda, Tomoya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90988", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Naraoka, Asuka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90989", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Naka, Hiroshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "90990", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-01-16"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "SubmittedText.pdf", "filesize": [{"value": "1.0 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1000000.0, "url": {"label": "SubmittedText", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/27947/files/SubmittedText.pdf"}, "version_id": "fd824978-e6e3-4569-b451-d57555041749"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Catalytic Transfer Hydration of Cyanohydrins to α-Hydroxyamides", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Catalytic Transfer Hydration of Cyanohydrins to α-Hydroxyamides", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1919"], "permalink_uri": "http://hdl.handle.net/2237/00030146", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-05-09"}, "publish_date": "2019-05-09", "publish_status": "0", "recid": "27947", "relation": {}, "relation_version_is_last": true, "title": ["Catalytic Transfer Hydration of Cyanohydrins to α-Hydroxyamides"], "weko_shared_id": -1}