{"_buckets": {"deposit": "0d805637-c4b3-425f-b11a-9902f6452286"}, "_deposit": {"id": "30140", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30140"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030140"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-04-06", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "15", "bibliographicPageEnd": "6257", "bibliographicPageStart": "6253", "bibliographicVolumeNumber": "59", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A total synthesis of tetrodotoxin was accomplished. A Diels\u2013Alder reaction between a known enone and a siloxy diene gave a tricyclic product, the steric bias of which was used to construct the remaining stereogenic centers. A nitrogen atom was introduced either by a four\u2010step sequence involving a Curtius rearrangement, or a three\u2010step sequence featuring a newly developed transformation of a terminal alkyne into a nitrile. Introduction of the guanidine moiety followed by the formation of the heterocyclic system by cascade reactions led to tetrodotoxin.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-04-06", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201916611", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [K. Murakami, T. Toma, T. Fukuyama, S. Yokoshima, Angew. Chem. Int. Ed. 2020 , 59 , 6253.], which has been published in final form at [https://doi.org/10.1002/anie.201916611]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Murakami, Keigo"}], "nameIdentifiers": [{"nameIdentifier": "99491", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toma, Tatsuya"}], "nameIdentifiers": [{"nameIdentifier": "99492", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukuyama, Tohru"}], "nameIdentifiers": [{"nameIdentifier": "99493", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoshima, Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "99494", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-04-06"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20200122_ttx_ACIE_revision_tc.pdf", "filesize": [{"value": "759.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 759000.0, "url": {"label": "20200122_ttx_ACIE_revision_tc", "url": "https://nagoya.repo.nii.ac.jp/record/30140/files/20200122_ttx_ACIE_revision_tc.pdf"}, "version_id": "8c43f921-60ac-4bbc-a476-29c7af46ad4f"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Total Synthesis of Tetrodotoxin", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Total Synthesis of Tetrodotoxin"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/00032326", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-06-10"}, "publish_date": "2020-06-10", "publish_status": "0", "recid": "30140", "relation": {}, "relation_version_is_last": true, "title": ["Total Synthesis of Tetrodotoxin"], "weko_shared_id": null}