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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Total Synthesis of Tetrodotoxin

http://hdl.handle.net/2237/00032326
http://hdl.handle.net/2237/00032326
d0de72ad-24b8-4c99-929e-1275fbe992e0
名前 / ファイル ライセンス アクション
20200122_ttx_ACIE_revision_tc.pdf 20200122_ttx_ACIE_revision_tc (759.0 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-06-10
タイトル
タイトル Total Synthesis of Tetrodotoxin
言語 en
著者 Murakami, Keigo

× Murakami, Keigo

WEKO 99491

en Murakami, Keigo

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Toma, Tatsuya

× Toma, Tatsuya

WEKO 99492

en Toma, Tatsuya

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Fukuyama, Tohru

× Fukuyama, Tohru

WEKO 99493

en Fukuyama, Tohru

Search repository
Yokoshima, Satoshi

× Yokoshima, Satoshi

WEKO 99494

en Yokoshima, Satoshi

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
権利情報 This is the peer reviewed version of the following article: [K. Murakami, T. Toma, T. Fukuyama, S. Yokoshima, Angew. Chem. Int. Ed. 2020 , 59 , 6253.], which has been published in final form at [https://doi.org/10.1002/anie.201916611]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
抄録
内容記述 A total synthesis of tetrodotoxin was accomplished. A Diels–Alder reaction between a known enone and a siloxy diene gave a tricyclic product, the steric bias of which was used to construct the remaining stereogenic centers. A nitrogen atom was introduced either by a four‐step sequence involving a Curtius rearrangement, or a three‐step sequence featuring a newly developed transformation of a terminal alkyne into a nitrile. Introduction of the guanidine moiety followed by the formation of the heterocyclic system by cascade reactions led to tetrodotoxin.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-04-06
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201916611
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : Angewandte Chemie International Edition

巻 59, 号 15, p. 6253-6257, 発行日 2020-04-06
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