{"_buckets": {"deposit": "f580e141-beb9-4ae0-84a4-8776de21af34"}, "_deposit": {"id": "30542", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30542"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030542", "sets": ["322"]}, "author_link": ["101686", "101687", "101688"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-06-19", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "4892", "bibliographicPageStart": "4888", "bibliographicVolumeNumber": "22", "bibliographic_titles": [{"bibliographic_title": "Organic Letters", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The halogen-bonding interaction between I2 and N-iodosuccinimide (NIS) stabilized by a Lewis base (LB) has been explored. 1H NMR, nuclear Overhauser effect (NOE), and diffusion-ordered NMR spectroscopy (DOSY) suggest the generation of a 1:1:1 assembly, LB–I2–NIS. In contrast, when N-iodotrifluoromethanesulfonimide (INTf2) is used instead of NIS, LB–I5^+–LB is generated. On the basis of these results in combination with density functional theory (DFT) calculations, we propose a mechanism for the formation of I2–NIS and the subsequent generation of an active iodinating species LB–I^+.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2021-06-19", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.orglett.0c01735", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-3IRZKRT9IWGWNK2ERFHP].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "1523-7060", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Horibe, Takahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101686", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tsuji, Yasutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101687", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishihara, Kazuaki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101688", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-06-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "2nd_revised_manuscript.pdf", "filesize": [{"value": "1.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1500000.0, "url": {"label": "2nd_revised_manuscript", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/30542/files/2nd_revised_manuscript.pdf"}, "version_id": "5671c2cc-91c9-46b5-a27e-5cf243a72916"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Iodine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Reagents", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Halogen bonding", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Lewis bases", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cations", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00032727", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-10-14"}, "publish_date": "2020-10-14", "publish_status": "0", "recid": "30542", "relation": {}, "relation_version_is_last": true, "title": ["Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization"], "weko_shared_id": -1}