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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization

http://hdl.handle.net/2237/00032727
http://hdl.handle.net/2237/00032727
714f6d5c-ec8c-4b0e-b402-e25e2791b2be
名前 / ファイル ライセンス アクション
2nd_revised_manuscript.pdf 2nd_revised_manuscript (1.5 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-10-14
タイトル
タイトル Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization
言語 en
著者 Horibe, Takahiro

× Horibe, Takahiro

WEKO 101686

en Horibe, Takahiro

Search repository
Tsuji, Yasutaka

× Tsuji, Yasutaka

WEKO 101687

en Tsuji, Yasutaka

Search repository
Ishihara, Kazuaki

× Ishihara, Kazuaki

WEKO 101688

en Ishihara, Kazuaki

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-3IRZKRT9IWGWNK2ERFHP].”
キーワード
主題Scheme Other
主題 Iodine
キーワード
主題Scheme Other
主題 Reagents
キーワード
主題Scheme Other
主題 Halogen bonding
キーワード
主題Scheme Other
主題 Lewis bases
キーワード
主題Scheme Other
主題 Cations
抄録
内容記述 The halogen-bonding interaction between I2 and N-iodosuccinimide (NIS) stabilized by a Lewis base (LB) has been explored. 1H NMR, nuclear Overhauser effect (NOE), and diffusion-ordered NMR spectroscopy (DOSY) suggest the generation of a 1:1:1 assembly, LB–I2–NIS. In contrast, when N-iodotrifluoromethanesulfonimide (INTf2) is used instead of NIS, LB–I5^+–LB is generated. On the basis of these results in combination with density functional theory (DFT) calculations, we propose a mechanism for the formation of I2–NIS and the subsequent generation of an active iodinating species LB–I^+.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-06-19
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.orglett.0c01735
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 1523-7060
書誌情報 en : Organic Letters

巻 22, 号 12, p. 4888-4892, 発行日 2020-06-19
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