{"_buckets": {"deposit": "bea90cf8-607a-4592-8999-497b62ff4584"}, "_deposit": {"id": "5454", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "5454"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00005454", "sets": ["696"]}, "author_link": ["14048", "14049", "14050", "14051", "14052"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2000-12-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "9597", "bibliographicPageStart": "9593", "bibliographicVolumeNumber": "113", "bibliographic_titles": [{"bibliographic_title": "The Journal of Chemical Physics", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The oxidation states of Sm atoms in various fullerene cages are directly investigated by electron energy-loss spectroscopy. The observed peak positions of the M_45 edges of the Sm atom in Sm@C_2n [2n=74, 78, 80, 82 (isomers I, III), 84 (isomers I, II, III)] are apparently shifted to the lower binding energy region in comparison with those of a trivalent Sm^3+ in Sm_2O_3. The results indicate that the Sm atoms take +2 valence states irrespective of the fullerene cages. This observation is discussed based on a simple thermochemical cycle model. We also report that the Sm metallofullerenes have been converted to Sm carbide materials under a prolonged electron beam irradiation.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/7059"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Institute of Physics", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1063/1.1321047", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright (2000) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0021-9606", "subitem_source_identifier_type": "PISSN"}]}, "item_10_text_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Okazaki, Toshiya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14048", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suenaga, Kazutomo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14049", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lian, Yongfu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14050", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Gu, Zhennan", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14051", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinohara, Hisanori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14052", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JChemPhys_113_9593.pdf", "filesize": [{"value": "85.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 85200.0, "url": {"label": "JChemPhys_113_9593.pdf", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/5454/files/JChemPhys_113_9593.pdf"}, "version_id": "cf28b52d-5054-4d00-abd4-8f7f877c8a2a"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/7059", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2006-10-25"}, "publish_date": "2006-10-25", "publish_status": "0", "recid": "5454", "relation": {}, "relation_version_is_last": true, "title": ["Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)"], "weko_shared_id": -1}